Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands

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Auteur principal: Norma Aidé Cortez
Format: Artículo científico
Langue:en
Publié: Sociedad Química de México 2004
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author Norma Aidé Cortez
author_facet Norma Aidé Cortez
contents Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands Norma Aidé Cortez Lars H. Hellberg Lucía Z. Flores López Ratnasamy Somanathan Miguel Parra Hake Gerardo Aguirre Multidisciplinaria (Ciencias Naturales y Exactas) meso Chiral Schiff base ring opening phenyllithium A library of chiral Schiff base ligands was synthesizedfrom aromatic aldehydes and chiral amino alcohols. These ligandswere then screened as catalysts in the asymmetric ring opening ofmeso-cyclohexene epoxide with phenyllithium to give (1S,2R)-phenylcyclohexanol in 9-67% ee. 2004 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47548111 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.1 Vol.48
format Artículo científico
id redalyc_47548111
institution Redalyc
language en
publishDate 2004
publisher Sociedad Química de México
spellingShingle Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
Norma Aidé Cortez
Multidisciplinaria (Ciencias Naturales y Exactas)
meso
Chiral
Schiff base
ring opening
phenyllithium
Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands Norma Aidé Cortez Lars H. Hellberg Lucía Z. Flores López Ratnasamy Somanathan Miguel Parra Hake Gerardo Aguirre Multidisciplinaria (Ciencias Naturales y Exactas) meso Chiral Schiff base ring opening phenyllithium A library of chiral Schiff base ligands was synthesizedfrom aromatic aldehydes and chiral amino alcohols. These ligandswere then screened as catalysts in the asymmetric ring opening ofmeso-cyclohexene epoxide with phenyllithium to give (1S,2R)-phenylcyclohexanol in 9-67% ee. 2004 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47548111 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.1 Vol.48
title Enantioselective Ring Opening of meso-Cyclohexene Epoxide with Phenyllithium Catalyzed by Chiral Schiff Base Ligands
topic Multidisciplinaria (Ciencias Naturales y Exactas)
meso
Chiral
Schiff base
ring opening
phenyllithium
url https://www.redalyc.org/articulo.oa?id=47548111