Synthesis and Structural Characterization of [BmMeBenz]2Ca(THF)2: Ca•••H–B interactions in a Sulfur-Rich Coordination Environment
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| Format: | Artículo científico |
| Language: | en |
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Sociedad Química de México
2017
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| _version_ | 1876462940474834944 |
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| author | Neena Chakrabarti |
| author_facet | Neena Chakrabarti |
| contents | Synthesis and Structural Characterization of [BmMeBenz]2Ca(THF)2: Ca•••H–B interactions in a Sulfur-Rich Coordination Environment Neena Chakrabarti Patrick J. Quinlivan Gerard Parkin Multidisciplinaria (Ciencias Naturales y Exactas) Calcium coordinate borohydride ray structure bis(mercaptoimidazolyl)hydroborato The bis(mercaptoimidazolyl)hydroborato calcium compound, [BmMeBenz]2Ca(THF)2, may be obtained by the reaction of Ca(BH4)2•2(THF) with 1-methyl-1,3-dihydro-2H-benzimidazole- 2-thione. X-ray diffraction demonstrates that the [BmMeBenz] ligands coordinate in a k3–S2H manner such that the calcium is eight-coordinate with a dodecahedral geometry that features two Ca•••H–B interactions. 2017 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47552182003 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.2 Vol.61 |
| format | Artículo científico |
| id | redalyc_47552182003 |
| institution | Redalyc |
| language | en |
| publishDate | 2017 |
| publisher | Sociedad Química de México |
| spellingShingle | Synthesis and Structural Characterization of [BmMeBenz]2Ca(THF)2: Ca•••H–B interactions in a Sulfur-Rich Coordination Environment Neena Chakrabarti Multidisciplinaria (Ciencias Naturales y Exactas) Calcium coordinate borohydride ray structure bis(mercaptoimidazolyl)hydroborato Synthesis and Structural Characterization of [BmMeBenz]2Ca(THF)2: Ca•••H–B interactions in a Sulfur-Rich Coordination Environment Neena Chakrabarti Patrick J. Quinlivan Gerard Parkin Multidisciplinaria (Ciencias Naturales y Exactas) Calcium coordinate borohydride ray structure bis(mercaptoimidazolyl)hydroborato The bis(mercaptoimidazolyl)hydroborato calcium compound, [BmMeBenz]2Ca(THF)2, may be obtained by the reaction of Ca(BH4)2•2(THF) with 1-methyl-1,3-dihydro-2H-benzimidazole- 2-thione. X-ray diffraction demonstrates that the [BmMeBenz] ligands coordinate in a k3–S2H manner such that the calcium is eight-coordinate with a dodecahedral geometry that features two Ca•••H–B interactions. 2017 artículo científico 1870-249X https://www.redalyc.org/articulo.oa?id=47552182003 en http://www.redalyc.org/revista.oa?id=475 Journal of the Mexican Chemical Society application/pdf Sociedad Química de México Journal of the Mexican Chemical Society (México) Num.2 Vol.61 |
| title | Synthesis and Structural Characterization of [BmMeBenz]2Ca(THF)2: Ca•••H–B interactions in a Sulfur-Rich Coordination Environment |
| topic | Multidisciplinaria (Ciencias Naturales y Exactas) Calcium coordinate borohydride ray structure bis(mercaptoimidazolyl)hydroborato |
| url | https://www.redalyc.org/articulo.oa?id=47552182003 |