Operational speciation of Cd, Cr, Cu, Mn, Ni, Pb, V and Zn in dust samples from schools in Caracas, Venezuela

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Autor principal: H. HANDT
Formato: Artículo científico
Lenguaje:en
Publicado: Universidad Nacional Autónoma de México 2008
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author H. HANDT
author_facet H. HANDT
contents Operational speciation of Cd, Cr, Cu, Mn, Ni, Pb, V and Zn in dust samples from schools in Caracas, Venezuela H. HANDT R. FERNÁNDEZ Z. BENZO C. GÓMEZ E. MARCANO F. GALÁRRAGA R. GONZÁLEZ Biología dust metals schools Operational speciation A sequential extraction approach has been applied to analyze Cd, Cr, Cu, Mn, Ni, Pb, V and Zn in dust samples from different schools chosen according with their location in areas with different concentrations of total suspended particles (TSP). The aim of this work is to provide information about the chemical fractionation of metal content. Hence, information about the origin, mode of occurrence, mobilization and transport of metals could be obtained. Total and partial metal concentrations were further determined by analyzing the samples after acid digestion procedure. The results compare very well for both methods. The metals are associated with various chemical forms as distinguished by sequential chemical extraction. The carbonate and Fe-Mn oxide phases dominate for Pb, Zn and Cu, whereas for Ni the organic phase is most important. V, Mn, Cr, Cd are mainly present in the oxide phases, however they are too in a residual phase but in minor proportion. The different sources for the elements studied are supported by the results from multivariate (PCA) analysis. 2008 artículo científico 0187-6236 https://www.redalyc.org/articulo.oa?id=56512095002 en http://www.redalyc.org/revista.oa?id=565 Atmósfera application/pdf Universidad Nacional Autónoma de México Atmósfera (México) Num.4 Vol.21
format Artículo científico
id redalyc_56512095002
institution Redalyc
language en
publishDate 2008
publisher Universidad Nacional Autónoma de México
spellingShingle Operational speciation of Cd, Cr, Cu, Mn, Ni, Pb, V and Zn in dust samples from schools in Caracas, Venezuela
H. HANDT
Biología
dust
metals
schools
Operational speciation
Operational speciation of Cd, Cr, Cu, Mn, Ni, Pb, V and Zn in dust samples from schools in Caracas, Venezuela H. HANDT R. FERNÁNDEZ Z. BENZO C. GÓMEZ E. MARCANO F. GALÁRRAGA R. GONZÁLEZ Biología dust metals schools Operational speciation A sequential extraction approach has been applied to analyze Cd, Cr, Cu, Mn, Ni, Pb, V and Zn in dust samples from different schools chosen according with their location in areas with different concentrations of total suspended particles (TSP). The aim of this work is to provide information about the chemical fractionation of metal content. Hence, information about the origin, mode of occurrence, mobilization and transport of metals could be obtained. Total and partial metal concentrations were further determined by analyzing the samples after acid digestion procedure. The results compare very well for both methods. The metals are associated with various chemical forms as distinguished by sequential chemical extraction. The carbonate and Fe-Mn oxide phases dominate for Pb, Zn and Cu, whereas for Ni the organic phase is most important. V, Mn, Cr, Cd are mainly present in the oxide phases, however they are too in a residual phase but in minor proportion. The different sources for the elements studied are supported by the results from multivariate (PCA) analysis. 2008 artículo científico 0187-6236 https://www.redalyc.org/articulo.oa?id=56512095002 en http://www.redalyc.org/revista.oa?id=565 Atmósfera application/pdf Universidad Nacional Autónoma de México Atmósfera (México) Num.4 Vol.21
title Operational speciation of Cd, Cr, Cu, Mn, Ni, Pb, V and Zn in dust samples from schools in Caracas, Venezuela
topic Biología
dust
metals
schools
Operational speciation
url https://www.redalyc.org/articulo.oa?id=56512095002