Photochromic properties of azo dye polymer thin films: evidence of an additional reversible mechanism of molecular behaviour

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1. Verfasser: G. Vitrant
Format: Artículo científico
Sprache:en
Veröffentlicht: Sociedad Mexicana de Física A.C. 2006
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author G. Vitrant
author_facet G. Vitrant
contents Photochromic properties of azo dye polymer thin films: evidence of an additional reversible mechanism of molecular behaviour G. Vitrant P. A. Chollet F. Kajzar A. Rodríguez Física, Astronomía y Matemáticas optical waveguides Photochromic polymers photoinduced refractive index Photoinduced refractive index and absorption anisotropies in thin films of an azo dye polymer have been carried out by pump-probe experiments. A refractive index change of Δn=-0.04 was obtained by independently measuring the two indices, parallel and perpendicular to pump light polarization. A long-term stability of the induced birefringence and a reversible photoinduced memory effect have been observed. The experimental results cannot be completely explained by the proposed photoisomerization models to describe the process involved. 2006 artículo científico 0035-001X https://www.redalyc.org/articulo.oa?id=57065006 en http://www.redalyc.org/revista.oa?id=570 Revista Mexicana de Física application/pdf Sociedad Mexicana de Física A.C. Revista Mexicana de Física (México) Num.2 Vol.52
format Artículo científico
id redalyc_57065006
institution Redalyc
language en
publishDate 2006
publisher Sociedad Mexicana de Física A.C.
spellingShingle Photochromic properties of azo dye polymer thin films: evidence of an additional reversible mechanism of molecular behaviour
G. Vitrant
Física, Astronomía y Matemáticas
optical waveguides
Photochromic polymers
photoinduced refractive index
Photochromic properties of azo dye polymer thin films: evidence of an additional reversible mechanism of molecular behaviour G. Vitrant P. A. Chollet F. Kajzar A. Rodríguez Física, Astronomía y Matemáticas optical waveguides Photochromic polymers photoinduced refractive index Photoinduced refractive index and absorption anisotropies in thin films of an azo dye polymer have been carried out by pump-probe experiments. A refractive index change of Δn=-0.04 was obtained by independently measuring the two indices, parallel and perpendicular to pump light polarization. A long-term stability of the induced birefringence and a reversible photoinduced memory effect have been observed. The experimental results cannot be completely explained by the proposed photoisomerization models to describe the process involved. 2006 artículo científico 0035-001X https://www.redalyc.org/articulo.oa?id=57065006 en http://www.redalyc.org/revista.oa?id=570 Revista Mexicana de Física application/pdf Sociedad Mexicana de Física A.C. Revista Mexicana de Física (México) Num.2 Vol.52
title Photochromic properties of azo dye polymer thin films: evidence of an additional reversible mechanism of molecular behaviour
topic Física, Astronomía y Matemáticas
optical waveguides
Photochromic polymers
photoinduced refractive index
url https://www.redalyc.org/articulo.oa?id=57065006