High resolution (3+1) REMPI and dissociation of acetone via 3pÃn Rydberg transitions

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Auteur principal: E. Mejía-Ospino
Format: Artículo científico
Langue:en
Publié: Sociedad Mexicana de Física A.C. 2006
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author E. Mejía-Ospino
author_facet E. Mejía-Ospino
contents High resolution (3+1) REMPI and dissociation of acetone via 3pÃn Rydberg transitions E. Mejía-Ospino I. Alvarez C. Cisneros Física, Astronomía y Matemáticas REMPI acetone Rydberg states Rydberg transition Measurements of multiphoton ionization and dissociation of acetone are reported in the wavelength range 490.0-510.0 nm at 1 nm intervals.To our knowledge there are no available results of (3+1) REMPI on acetone in this region. The experiments were performed using anNd:YAG-OPO (optical parametric oscillator) laser system coupled to a time-of-flight mass spectrometer. The experimental results show twodissociation channels of the acetone ion, leading to the products (CH3CO+) and (CH+3 ), the channel CH3COCH+3 !CH3CO+ + CH3 beingthe most favored. The acetone and acetyl ions are observed in the entire wavelength range investigated. Finally, the three-photon resonancemultiphoton spectrum of the acetone 3pÃn Rydberg transition is also reported. 2006 artículo científico 0035-001X https://www.redalyc.org/articulo.oa?id=57065212 en http://www.redalyc.org/revista.oa?id=570 Revista Mexicana de Física application/pdf Sociedad Mexicana de Física A.C. Revista Mexicana de Física (México) Num.4 Vol.52
format Artículo científico
id redalyc_57065212
institution Redalyc
language en
publishDate 2006
publisher Sociedad Mexicana de Física A.C.
spellingShingle High resolution (3+1) REMPI and dissociation of acetone via 3pÃn Rydberg transitions
E. Mejía-Ospino
Física, Astronomía y Matemáticas
REMPI
acetone
Rydberg states
Rydberg transition
High resolution (3+1) REMPI and dissociation of acetone via 3pÃn Rydberg transitions E. Mejía-Ospino I. Alvarez C. Cisneros Física, Astronomía y Matemáticas REMPI acetone Rydberg states Rydberg transition Measurements of multiphoton ionization and dissociation of acetone are reported in the wavelength range 490.0-510.0 nm at 1 nm intervals.To our knowledge there are no available results of (3+1) REMPI on acetone in this region. The experiments were performed using anNd:YAG-OPO (optical parametric oscillator) laser system coupled to a time-of-flight mass spectrometer. The experimental results show twodissociation channels of the acetone ion, leading to the products (CH3CO+) and (CH+3 ), the channel CH3COCH+3 !CH3CO+ + CH3 beingthe most favored. The acetone and acetyl ions are observed in the entire wavelength range investigated. Finally, the three-photon resonancemultiphoton spectrum of the acetone 3pÃn Rydberg transition is also reported. 2006 artículo científico 0035-001X https://www.redalyc.org/articulo.oa?id=57065212 en http://www.redalyc.org/revista.oa?id=570 Revista Mexicana de Física application/pdf Sociedad Mexicana de Física A.C. Revista Mexicana de Física (México) Num.4 Vol.52
title High resolution (3+1) REMPI and dissociation of acetone via 3pÃn Rydberg transitions
topic Física, Astronomía y Matemáticas
REMPI
acetone
Rydberg states
Rydberg transition
url https://www.redalyc.org/articulo.oa?id=57065212