Hydrocarbon synthesis using Iron and Ruthenium/SiO2 with FISCHER-TROPSCH catalysis

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Autore principale: Y.J. Fonseca
Natura: Artículo científico
Lingua:en
Pubblicazione: Universidad de los Andes 2007
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author Y.J. Fonseca
author_facet Y.J. Fonseca
contents Hydrocarbon synthesis using Iron and Ruthenium/SiO2 with FISCHER-TROPSCH catalysis Y.J. Fonseca A. Loaiza M. Briceño B. Fontal M. Reyes T. Suárez F. Bellandi R. R. Contreras P. Cancines Química syngas Fischer Tropsch catalyst nanoparticles Fe2(CO)9, Fe3(CO)12 and Ru3(CO)12 clusters were used as precursors for silica supported metals. The impregnated silica solids were obtained in organic solvents under inert atmosphere and the adsorbed complexes and reduced metals characterized by FT-IR, SEM EDX and HRTEM. The catalysts showed good Fischer–Tropsch (FT) activity; the main products were alkanes, alkenes and medium and higher alcohols as analyzed by GCMS. The Ru catalysts showed higher alcohols selectivity. HRTEM showed Ru nanoparticle size. 2007 artículo científico 1856-5301 https://www.redalyc.org/articulo.oa?id=93320304 en http://www.redalyc.org/revista.oa?id=933 Avances en Química application/pdf Universidad de los Andes Avances en Química (República Bolivariana de Venezuela) Num.3 Vol.2
format Artículo científico
id redalyc_93320304
institution Redalyc
language en
publishDate 2007
publisher Universidad de los Andes
spellingShingle Hydrocarbon synthesis using Iron and Ruthenium/SiO2 with FISCHER-TROPSCH catalysis
Y.J. Fonseca
Química
syngas
Fischer
Tropsch
catalyst
nanoparticles
Hydrocarbon synthesis using Iron and Ruthenium/SiO2 with FISCHER-TROPSCH catalysis Y.J. Fonseca A. Loaiza M. Briceño B. Fontal M. Reyes T. Suárez F. Bellandi R. R. Contreras P. Cancines Química syngas Fischer Tropsch catalyst nanoparticles Fe2(CO)9, Fe3(CO)12 and Ru3(CO)12 clusters were used as precursors for silica supported metals. The impregnated silica solids were obtained in organic solvents under inert atmosphere and the adsorbed complexes and reduced metals characterized by FT-IR, SEM EDX and HRTEM. The catalysts showed good Fischer–Tropsch (FT) activity; the main products were alkanes, alkenes and medium and higher alcohols as analyzed by GCMS. The Ru catalysts showed higher alcohols selectivity. HRTEM showed Ru nanoparticle size. 2007 artículo científico 1856-5301 https://www.redalyc.org/articulo.oa?id=93320304 en http://www.redalyc.org/revista.oa?id=933 Avances en Química application/pdf Universidad de los Andes Avances en Química (República Bolivariana de Venezuela) Num.3 Vol.2
title Hydrocarbon synthesis using Iron and Ruthenium/SiO2 with FISCHER-TROPSCH catalysis
topic Química
syngas
Fischer
Tropsch
catalyst
nanoparticles
url https://www.redalyc.org/articulo.oa?id=93320304