Shifting to the red the absorption edge in TiO2 films: a photoacoustic study

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Main Author: F. Gordillo-Delgado
Format: Artículo científico
Language:en
Published: Sociedad Mexicana de Ciencia y Tecnología de Superficies y Materiales A.C. 2011
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author F. Gordillo-Delgado
author_facet F. Gordillo-Delgado
contents Shifting to the red the absorption edge in TiO2 films: a photoacoustic study F. Gordillo-Delgado K. Villa-Gómez E. Marín Física, Astronomía y Matemáticas Sol gel Thin films Photoacoustic Photocatalysis When Titanium dioxide in contact with a polluted water sample is irradiated with ultraviolet light, electronhole pairs can be generated, which can react with oxygen and water producing free radicals that can degrade the pollutants, changing them into harmless compounds for the environment. The ultraviolet component of the solar radiation is around 7%. Therefore, it is convenient to modify the TiO2 films crystalline structure for obtaining photocatalytical processes with visible light. In this work we report on the growth of TiO2 thin films by the Sol-gel technique considering the incorporation of AgNO3 in the initial solution containing the precursor. The concentration of the AgNO3 saline solution was changed between 5 and 30% to control the grain size of the grown TiO2 nanocrystals, impregnating 6 layers over glass slide substrates and using a sintering temperature of 600 °C. The obtained films were characterized structurally by means of X-ray diffraction. The shift in the forbidden energy bandwidth value to the red part of the optical absorption spectrum was evidenced by Photoacoustic Spectroscopy. The photocatalytic activity was tested on a solution of methylene blue using also the Photoacoustic technique. 2011 artículo científico 1665-3521 https://www.redalyc.org/articulo.oa?id=94218546005 en http://www.redalyc.org/revista.oa?id=942 Superficies y vacío application/pdf Sociedad Mexicana de Ciencia y Tecnología de Superficies y Materiales A.C. Superficies y vacío (México) Num.1 Vol.24
format Artículo científico
id redalyc_94218546005
institution Redalyc
language en
publishDate 2011
publisher Sociedad Mexicana de Ciencia y Tecnología de Superficies y Materiales A.C.
spellingShingle Shifting to the red the absorption edge in TiO2 films: a photoacoustic study
F. Gordillo-Delgado
Física, Astronomía y Matemáticas
Sol
gel
Thin films
Photoacoustic
Photocatalysis
Shifting to the red the absorption edge in TiO2 films: a photoacoustic study F. Gordillo-Delgado K. Villa-Gómez E. Marín Física, Astronomía y Matemáticas Sol gel Thin films Photoacoustic Photocatalysis When Titanium dioxide in contact with a polluted water sample is irradiated with ultraviolet light, electronhole pairs can be generated, which can react with oxygen and water producing free radicals that can degrade the pollutants, changing them into harmless compounds for the environment. The ultraviolet component of the solar radiation is around 7%. Therefore, it is convenient to modify the TiO2 films crystalline structure for obtaining photocatalytical processes with visible light. In this work we report on the growth of TiO2 thin films by the Sol-gel technique considering the incorporation of AgNO3 in the initial solution containing the precursor. The concentration of the AgNO3 saline solution was changed between 5 and 30% to control the grain size of the grown TiO2 nanocrystals, impregnating 6 layers over glass slide substrates and using a sintering temperature of 600 °C. The obtained films were characterized structurally by means of X-ray diffraction. The shift in the forbidden energy bandwidth value to the red part of the optical absorption spectrum was evidenced by Photoacoustic Spectroscopy. The photocatalytic activity was tested on a solution of methylene blue using also the Photoacoustic technique. 2011 artículo científico 1665-3521 https://www.redalyc.org/articulo.oa?id=94218546005 en http://www.redalyc.org/revista.oa?id=942 Superficies y vacío application/pdf Sociedad Mexicana de Ciencia y Tecnología de Superficies y Materiales A.C. Superficies y vacío (México) Num.1 Vol.24
title Shifting to the red the absorption edge in TiO2 films: a photoacoustic study
topic Física, Astronomía y Matemáticas
Sol
gel
Thin films
Photoacoustic
Photocatalysis
url https://www.redalyc.org/articulo.oa?id=94218546005