Chemoselective Synthesis of α‐Chloro and α,α‐Dichloro Acetamidines via the Carbenoids Addition to Inherently Low Electrophilic Carbodiimides
Fuente:
Wiley Open Access
Saved in:
| Main Authors: | Davide Castiglione, Margherita Miele, Alberto Nardi, Laura Castoldi, Vittorio Pace |
|---|---|
| Format: | Artículo Open Access |
| Published: |
Wiley
2025
|
| Subjects: | |
| Online Access: | |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Similar Items
Ruppert‐Prakash Reagent (TMSCF3)‐Catalyzed Chemoselective Esterification of Weinreb Amides
by: Margherita Miele, et al.
Published: (2024)
by: Margherita Miele, et al.
Published: (2024)
Ruthenium(II)‐Catalyzed Pyridyl‐Directed Tryptophan C−H Acylmethylation with α‐Chloro Ketones
by: Shulei Hu, et al.
Published: (2024)
by: Shulei Hu, et al.
Published: (2024)
Synthesis of N,N‐Disubstituted Hydrazines by Electrocatalytic Addition of Hydrazines to α,β‐Unsaturated Carbonyl Compounds
by: Qingyu Xu, et al.
Published: (2024)
by: Qingyu Xu, et al.
Published: (2024)
Magnesium‐Mediated Reductive Defluorinative Cross‐Electrophile Coupling of α‐Trifluoromethyl Styrenes with CO2 and Acyl Imidazoles
by: Jianjun Hao, et al.
Published: (2025)
by: Jianjun Hao, et al.
Published: (2025)
Copper‐Catalyzed Coupling Reaction of Diazo Reagent with Formamide for the Synthesis of α‐Formyloxy Ketones and α‐Ketoamides
by: Rongxiang Chen, et al.
Published: (2025)
by: Rongxiang Chen, et al.
Published: (2025)
Stereoselective Synthesis of Aliphatic α‐Amino Acids by Chemo‐Enzymatic Hydroamination‐Hydrodesulfurisation
by: Celeste Nobbio, et al.
Published: (2024)
by: Celeste Nobbio, et al.
Published: (2024)
Electrochemical N‐hydroxyphthalimide Catalyzed Addition of α‐Alkoxy Radicals to Oxime Ethers
by: Rodrigo G. Enríquez, et al.
Published: (2026)
by: Rodrigo G. Enríquez, et al.
Published: (2026)
Magnesium‐Catalyzed Asymmetric Thia‐Michael Addition to α,β‐Unsaturated Ketones
by: Joanna A. Jaszczewska‐Adamczak, et al.
Published: (2024)
by: Joanna A. Jaszczewska‐Adamczak, et al.
Published: (2024)
K3PO4–Mediated Synthesis of Chromeno–[3,4‐c]isoxazole from 3–Nitro–2H–chromene and α–Chloro Aldehyde via Michael Addition/C−Cl Bond Cleavage/Deformylation as Key Fragmentation Sequences
by: Aniruddh Pratap, et al.
Published: (2024)
by: Aniruddh Pratap, et al.
Published: (2024)
Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands
by: Changxue Gu, et al.
Published: (2024)
by: Changxue Gu, et al.
Published: (2024)
Organocatalytic Stereoselective Decarboxylative Addition of α‐Amido Malonic Acid Half Oxyesters to Isatins
by: Kazuki Fujita, et al.
Published: (2024)
by: Kazuki Fujita, et al.
Published: (2024)
Continuous Flow Synthesis of α‐Chloroketones from Esters
by: Léna Brassart, et al.
Published: (2025)
by: Léna Brassart, et al.
Published: (2025)
Ru(II)‐Catalyzed Divergent Amidation and Homocoupling of β‐Ketosulfoxonium Ylides: Selective Access to α‐Ketoamides and α,α,β‐Tricarbonyl Sulfoxonium Ylides
by: Ajay Kant Gola, et al.
Published: (2025)
by: Ajay Kant Gola, et al.
Published: (2025)
α ‐Fluoroalkenylzinc Halide: Preparation, Stability, Structures, and Application to Monofluoroalkene Synthesis
by: Kazuhiro Morisaki, et al.
Published: (2025)
by: Kazuhiro Morisaki, et al.
Published: (2025)
Preparation of Mesoporous Cu2O Nanospheres for Green Synthesis in the Enantioselective Boron Conjugate Addition of α,β‐Unsaturated Chiral Compounds in Aqueous Phase
by: Xuhong Zhao, et al.
Published: (2025)
by: Xuhong Zhao, et al.
Published: (2025)
Biocatalytic Asymmetric Michael Addition of Thiols to α,β‐Unsaturated Aldehydes via Enzyme‐Bound Iminium Ion Intermediates
by: Michele Crotti, et al.
Published: (2026)
by: Michele Crotti, et al.
Published: (2026)
Catalytic Strategies for the Selective Synthesis of α‐ and β‐Functionalized Amines via Hydrofunctionalization of Enamides
by: Rui Sun, et al.
Published: (2024)
by: Rui Sun, et al.
Published: (2024)
Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes
by: Matthias R. Steiner, et al.
Published: (2025)
by: Matthias R. Steiner, et al.
Published: (2025)
Divergent Synthesis of Oxindole Derivatives via Cascade Deoxygenative Friedel–Crafts Cyclization of α ‐Ketoamides
by: Khyati Tripathi, et al.
Published: (2026)
by: Khyati Tripathi, et al.
Published: (2026)
Unveiling the Potential of a Cobalt‐Based Metal‐Organic Framework in Carbodiimide Synthesis
by: Daniël S. Verdoorn, et al.
Published: (2025)
by: Daniël S. Verdoorn, et al.
Published: (2025)
The Chemistry of α‐Enolizable Alkynones: A Comprehensive Review
by: Sofia O. Karnakova, et al.
Published: (2024)
by: Sofia O. Karnakova, et al.
Published: (2024)
Photocatalytic Oxidation of α‐Substituted Amines to Lactams/Amides
by: Manish Kumar, et al.
Published: (2024)
by: Manish Kumar, et al.
Published: (2024)
Visible‐light‐induced and EDA Complex‐initiated Hydroxyselenization of α ‐CF 3 Alkenes: Access to α ‐trifluoromethyl‐ β ‐selanyl tertiary Alcohols
by: Bin Wang, et al.
Published: (2025)
by: Bin Wang, et al.
Published: (2025)
Tunable Preparation of α‐Aminoacyl Fluorides and α‐Fluoroamides via Base‐Induced Cascade Multiple‐Cleavage Processes from Bromodifluorohydrin Reagents and Amines
by: Giulia De Santis, et al.
Published: (2025)
by: Giulia De Santis, et al.
Published: (2025)
Front Cover Picture: Palladium‐Catalyzed Chemoselective Amination of Chloro(hetero)aryl Triflates Enabled by Alkyl‐Pyrazole‐Based Phosphine Ligands (Adv. Synth. Catal. 7/2024)
by: Changxue Gu, et al.
Published: (2024)
by: Changxue Gu, et al.
Published: (2024)
Zn(II)‐Catalyzed Asymmetric Transfer Hydrogenation of γ‐Indolyl β,γ‐Unsaturated α‐Keto Amides and α‐Keto Esters with Hantzsch Ester
by: Xing‐Ping Zhang, et al.
Published: (2025)
by: Xing‐Ping Zhang, et al.
Published: (2025)
Electrochemical α‐Functionalization of N‐Aryl‐Activated Tertiary Amines
by: Feijun Wang, et al.
Published: (2024)
by: Feijun Wang, et al.
Published: (2024)
Functionalized α‐Fluorinated Amines from Imines and Enol Ethers
by: Dimitra Kyrko, et al.
Published: (2024)
by: Dimitra Kyrko, et al.
Published: (2024)
Organocatalytic Asymmetric Decarboxylative Mannich Reaction for the Synthesis of Non‐Natural α‐Amino Acids Bearing Alkynyl Groups
by: Xueting Xu, et al.
Published: (2024)
by: Xueting Xu, et al.
Published: (2024)
Biocatalytic Recycling Cascades Combining Aldolases and Transaminases for the Stereo‐Controlled Synthesis of γ‐Hydroxy‐α‐Amino Acids
by: Léa Gourbeyre, et al.
Published: (2024)
by: Léa Gourbeyre, et al.
Published: (2024)
Synthesis of gem‐Difluorocyclobutane‐Fused Indolines via Ruthenium‐Catalyzed Defluorinative Annulation of Trifluoromethyl Carbenoids with 2‐Alkenylanilines
by: Hao Tan, et al.
Published: (2024)
by: Hao Tan, et al.
Published: (2024)
Dinickel‐Catalyzed Enantioselective α ‐Amination of Ketones With Aliphatic Amino Group
by: Yuchi Zhao, et al.
Published: (2026)
by: Yuchi Zhao, et al.
Published: (2026)
Nickel‐Catalyzed Enantioselective α‐Allylation of Cyclic Ketones with Allylic Alcohols
by: Neng‐Quan Jiang, et al.
Published: (2024)
by: Neng‐Quan Jiang, et al.
Published: (2024)
Atom‐Economical Synthesis of Gem ‐Borylsilylalkanes by Copper‐Catalyzed SiH Bond Insertion of α ‐Furyl Boryl Carbenes
by: Daan Song, et al.
Published: (2026)
by: Daan Song, et al.
Published: (2026)
Three‐Component Synthesis of γ‐Amino Esters with α‐Quaternary Carbon Centers via NHC/Photoredox Dual Catalysis
by: Adam X. Wayment, et al.
Published: (2025)
by: Adam X. Wayment, et al.
Published: (2025)
One‐Step Copper‐Assisted Synthesis of α‐(Styrylsulfonyl)amides via SO 2 Incorporation Under Visible Light
by: Nejc Petek, et al.
Published: (2025)
by: Nejc Petek, et al.
Published: (2025)
Construction of α‐Pyrones and Enamine Derivatives via Divergent Transformations of β‐Aminoacrylates
by: Yong‐Tu Yuan, et al.
Published: (2025)
by: Yong‐Tu Yuan, et al.
Published: (2025)
Synthesis of Double‐Thio‐Functionalized Pentasubstituted Pyridines Using α‐Enemalononitrile Ketene Dithioacetals and Thiophenols and Their Selective Arylthio Substitution Reactions
by: Yongqin Hu, et al.
Published: (2026)
by: Yongqin Hu, et al.
Published: (2026)
Hydricity Modulated Methylation of Indoles and Nitriles Using Methanol: Selective Synthesis of C3‐Methylated Indoles, Bisindolylmethanes, and α‐Methylated Nitriles
by: Manoj Pradhan, et al.
Published: (2025)
by: Manoj Pradhan, et al.
Published: (2025)
Unsupported Nanoporous Copper Catalyzed Insertion of Carbenes from α‐Diazo Compounds into Hydrosilanes
by: Ruyi Jiang, et al.
Published: (2024)
by: Ruyi Jiang, et al.
Published: (2024)
Similar Items
-
Ruppert‐Prakash Reagent (TMSCF3)‐Catalyzed Chemoselective Esterification of Weinreb Amides
by: Margherita Miele, et al.
Published: (2024) -
Ruthenium(II)‐Catalyzed Pyridyl‐Directed Tryptophan C−H Acylmethylation with α‐Chloro Ketones
by: Shulei Hu, et al.
Published: (2024) -
Synthesis of N,N‐Disubstituted Hydrazines by Electrocatalytic Addition of Hydrazines to α,β‐Unsaturated Carbonyl Compounds
by: Qingyu Xu, et al.
Published: (2024) -
Magnesium‐Mediated Reductive Defluorinative Cross‐Electrophile Coupling of α‐Trifluoromethyl Styrenes with CO2 and Acyl Imidazoles
by: Jianjun Hao, et al.
Published: (2025) -
Copper‐Catalyzed Coupling Reaction of Diazo Reagent with Formamide for the Synthesis of α‐Formyloxy Ketones and α‐Ketoamides
by: Rongxiang Chen, et al.
Published: (2025)