Study on the effect of chain extenders on aliphatic polyurethane and its application

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Hauptverfasser: Wenhe Ding, Hongyan Liu, Yanyan Bo, Siqi Zhan, Zaiqian Yu, Yuting Zhang, Ruize Yuan, Shiwei Wang, Mingyao Zhang
Format: Artículo Open Access
Veröffentlicht: Wiley 2024
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author Wenhe Ding
Hongyan Liu
Yanyan Bo
Siqi Zhan
Zaiqian Yu
Yuting Zhang
Ruize Yuan
Shiwei Wang
Mingyao Zhang
author_facet Wenhe Ding
Hongyan Liu
Yanyan Bo
Siqi Zhan
Zaiqian Yu
Yuting Zhang
Ruize Yuan
Shiwei Wang
Mingyao Zhang
Wenhe Ding
Hongyan Liu
Yanyan Bo
Siqi Zhan
Zaiqian Yu
Yuting Zhang
Ruize Yuan
Shiwei Wang
Mingyao Zhang
collection Wiley Open Access
contents Study on the effect of chain extenders on aliphatic polyurethane and its application Wenhe Ding Hongyan Liu Yanyan Bo Siqi Zhan Zaiqian Yu Yuting Zhang Ruize Yuan Shiwei Wang Mingyao Zhang Journal of Applied Polymer Science AbstractThermoplastic polyurethane (TPU) has been applied to high‐performance laminated glass depending on its high impact strength and bonding properties. The utilization of various polyurethane molecular structures in laminated glass is scarcely reported. The selection and application of chain extenders are crucial for TPU performance. In this work, aliphatic polyurethane film with high strength has been successfully synthesized, incorporating chain extender of poly(propylene glycol) bis(2‐aminopropyl ether) (PEA230). The films with melting point above 80°C were prepared by adjusting the proportion of dimethylglyoxime (DMG), while simultaneously monitoring the thermal behavior of the samples by DMA. Results indicate that combining PEA230 and DMG in a 1:1 molar ratio yields the hydrogen bonding degree of 85.77%, toughness of 43.14 MJ m3, and shear stress of 1.8 MPa for the polyurethane film. Subsequently, laminated glasses based on the polyurethane film with different thermal properties were constructed successfully, and their super strong impact resistance was confirmed through falling ball impact experiments. 10.1002/app.55445 http://onlinelibrary.wiley.com/termsAndConditions#vor
doi_str_mv 10.1002/app.55445
format Artículo Open Access
id wiley_oa_10_1002_app_55445
institution Wiley Open Access
license_str_mv http://onlinelibrary.wiley.com/termsAndConditions#vor
publishDate 2024
publisher Wiley
record_format wiley_oa
spellingShingle Study on the effect of chain extenders on aliphatic polyurethane and its application
Wenhe Ding
Hongyan Liu
Yanyan Bo
Siqi Zhan
Zaiqian Yu
Yuting Zhang
Ruize Yuan
Shiwei Wang
Mingyao Zhang
Journal of Applied Polymer Science
Study on the effect of chain extenders on aliphatic polyurethane and its application Wenhe Ding Hongyan Liu Yanyan Bo Siqi Zhan Zaiqian Yu Yuting Zhang Ruize Yuan Shiwei Wang Mingyao Zhang Journal of Applied Polymer Science AbstractThermoplastic polyurethane (TPU) has been applied to high‐performance laminated glass depending on its high impact strength and bonding properties. The utilization of various polyurethane molecular structures in laminated glass is scarcely reported. The selection and application of chain extenders are crucial for TPU performance. In this work, aliphatic polyurethane film with high strength has been successfully synthesized, incorporating chain extender of poly(propylene glycol) bis(2‐aminopropyl ether) (PEA230). The films with melting point above 80°C were prepared by adjusting the proportion of dimethylglyoxime (DMG), while simultaneously monitoring the thermal behavior of the samples by DMA. Results indicate that combining PEA230 and DMG in a 1:1 molar ratio yields the hydrogen bonding degree of 85.77%, toughness of 43.14 MJ m3, and shear stress of 1.8 MPa for the polyurethane film. Subsequently, laminated glasses based on the polyurethane film with different thermal properties were constructed successfully, and their super strong impact resistance was confirmed through falling ball impact experiments. 10.1002/app.55445 http://onlinelibrary.wiley.com/termsAndConditions#vor
title Study on the effect of chain extenders on aliphatic polyurethane and its application
topic Journal of Applied Polymer Science
url https://onlinelibrary.wiley.com/doi/10.1002/app.55445