Preparation of thermally conductive polyimide/aluminum oxide/boehmite composite separators for enhancing lithium‐ion battery safety and performance
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| Natura: | Artículo Open Access |
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Wiley
2024
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| _version_ | 1867020344040095744 |
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| author | Dong Haolin Weiwei Cui Huang Yunlong Chen Xin Ding Yubo |
| author_facet | Dong Haolin Weiwei Cui Huang Yunlong Chen Xin Ding Yubo Dong Haolin Weiwei Cui Huang Yunlong Chen Xin Ding Yubo |
| collection | Wiley Open Access |
| contents | Preparation of thermally conductive polyimide/aluminum oxide/boehmite composite separators for enhancing lithium‐ion battery safety and performance Dong Haolin Weiwei Cui Huang Yunlong Chen Xin Ding Yubo Journal of Applied Polymer Science AbstractThis study endeavors to enhance the safety of lithium‐ion batteries (LIBs) by synthesizing a polyamide acid (PAA)/Al2O3 composite spinning solution using 4,4′‐diaminodiphenyl ether (ODA) and pyromellitic anhydride (PMDA) as monomers, and nano‐Al2O3 as a thermal conductivity filler. Subsequently, the PAA/Al2O3 fiber membrane is fabricated via electrostatic spinning, followed by gradient heating imidization to produce a polyimide (PI)/Al2O3 composite membrane. This membrane is then dipped into a boron nitride (BM) slurry to ultimately yield an organic–inorganic PI/Al2O3/BM composite separator with superior flame‐retardant and thermal conductivity properties. The thermal stability, flame retardancy, electrolyte wettability, mechanical integrity, and cycle rate performance of the composite membranes are rigorously evaluated. The results demonstrate that the PI/5% Al2O3/BM composite membrane exhibits the most favorable overall performance, with no shrinkage observed at 200°C and no significant changes after sustained ignition for 10 s. The incorporation of the thermal conductivity Al2O3 filler significantly enhances the heat transfer properties of the composite separator. The room temperature ionic conductivity reaches 2.786 mS cm−1 after electrolyte absorption, and the initial discharge capacity of the assembled battery is 156.28 mAhg−1. Following 100 charge/discharge cycles at 0.2C, the capacity retention rate is 97.7%, and at a discharge rate of 5C, the capacity retention rate is 74.9%. 10.1002/app.56049 http://onlinelibrary.wiley.com/termsAndConditions#vor |
| doi_str_mv | 10.1002/app.56049 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_app_56049 |
| institution | Wiley Open Access |
| license_str_mv | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| publishDate | 2024 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Preparation of thermally conductive polyimide/aluminum oxide/boehmite composite separators for enhancing lithium‐ion battery safety and performance Dong Haolin Weiwei Cui Huang Yunlong Chen Xin Ding Yubo Journal of Applied Polymer Science Preparation of thermally conductive polyimide/aluminum oxide/boehmite composite separators for enhancing lithium‐ion battery safety and performance Dong Haolin Weiwei Cui Huang Yunlong Chen Xin Ding Yubo Journal of Applied Polymer Science AbstractThis study endeavors to enhance the safety of lithium‐ion batteries (LIBs) by synthesizing a polyamide acid (PAA)/Al2O3 composite spinning solution using 4,4′‐diaminodiphenyl ether (ODA) and pyromellitic anhydride (PMDA) as monomers, and nano‐Al2O3 as a thermal conductivity filler. Subsequently, the PAA/Al2O3 fiber membrane is fabricated via electrostatic spinning, followed by gradient heating imidization to produce a polyimide (PI)/Al2O3 composite membrane. This membrane is then dipped into a boron nitride (BM) slurry to ultimately yield an organic–inorganic PI/Al2O3/BM composite separator with superior flame‐retardant and thermal conductivity properties. The thermal stability, flame retardancy, electrolyte wettability, mechanical integrity, and cycle rate performance of the composite membranes are rigorously evaluated. The results demonstrate that the PI/5% Al2O3/BM composite membrane exhibits the most favorable overall performance, with no shrinkage observed at 200°C and no significant changes after sustained ignition for 10 s. The incorporation of the thermal conductivity Al2O3 filler significantly enhances the heat transfer properties of the composite separator. The room temperature ionic conductivity reaches 2.786 mS cm−1 after electrolyte absorption, and the initial discharge capacity of the assembled battery is 156.28 mAhg−1. Following 100 charge/discharge cycles at 0.2C, the capacity retention rate is 97.7%, and at a discharge rate of 5C, the capacity retention rate is 74.9%. 10.1002/app.56049 http://onlinelibrary.wiley.com/termsAndConditions#vor |
| title | Preparation of thermally conductive polyimide/aluminum oxide/boehmite composite separators for enhancing lithium‐ion battery safety and performance |
| topic | Journal of Applied Polymer Science |
| url | https://onlinelibrary.wiley.com/doi/10.1002/app.56049 |