Synergistic Reinforcement of Ethylene–Butene–Terpolymer Rubber by Graphene and Zinc Dimethacrylate: Multicrosslinking and Underlying Mechanisms

Fuente: Wiley Open Access
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Auteurs principaux: Li Zhang, Jianming Liu, Duanjiao Li, Wenxing Sun, Zhi Li, Yongchao Liang, Qiang Fu, Nian Tang, Pengxiang Bai, Yuqi Wang, Jiuming Liang
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Publié: Wiley 2025
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author Li Zhang
Jianming Liu
Duanjiao Li
Wenxing Sun
Zhi Li
Yongchao Liang
Qiang Fu
Nian Tang
Pengxiang Bai
Yuqi Wang
Jiuming Liang
author_facet Li Zhang
Jianming Liu
Duanjiao Li
Wenxing Sun
Zhi Li
Yongchao Liang
Qiang Fu
Nian Tang
Pengxiang Bai
Yuqi Wang
Jiuming Liang
Li Zhang
Jianming Liu
Duanjiao Li
Wenxing Sun
Zhi Li
Yongchao Liang
Qiang Fu
Nian Tang
Pengxiang Bai
Yuqi Wang
Jiuming Liang
collection Wiley Open Access
contents Synergistic Reinforcement of Ethylene–Butene–Terpolymer Rubber by Graphene and Zinc Dimethacrylate: Multicrosslinking and Underlying Mechanisms Li Zhang Jianming Liu Duanjiao Li Wenxing Sun Zhi Li Yongchao Liang Qiang Fu Nian Tang Pengxiang Bai Yuqi Wang Jiuming Liang Journal of Applied Polymer Science ABSTRACTThe growing demand for advanced rubber composites highlights the need for enhanced performance and durability. This study explores the synergistic reinforcement effect of graphene nanosheets (GNs) and zinc dimethacrylate (ZDMA) on ethylene–butene–terpolymer (EBT) composites, focusing on their microscopic reinforcement mechanisms. In situ‐modified GNs and ZDMA are employed for co‐crosslinking. The impact of varying GNs contents and ZDMA ratios is analyzed, with a focus on their effects on the material's mechanical, thermal, and dynamic properties. GNs significantly enhance tensile strength, elongation at break, and hysteresis heat generation, while ZDMA further improves strength and thermal stability by optimizing the crosslinking network. Their synergy markedly boosts the performance of EBT composites, making them ideal for high‐strength, high‐temperature applications. The study provides design guidelines for advanced automotive rubber components and lays a foundation for optimizing EBT composites. 10.1002/app.57134 http://onlinelibrary.wiley.com/termsAndConditions#vor
doi_str_mv 10.1002/app.57134
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institution Wiley Open Access
license_str_mv http://onlinelibrary.wiley.com/termsAndConditions#vor
publishDate 2025
publisher Wiley
record_format wiley_oa
spellingShingle Synergistic Reinforcement of Ethylene–Butene–Terpolymer Rubber by Graphene and Zinc Dimethacrylate: Multicrosslinking and Underlying Mechanisms
Li Zhang
Jianming Liu
Duanjiao Li
Wenxing Sun
Zhi Li
Yongchao Liang
Qiang Fu
Nian Tang
Pengxiang Bai
Yuqi Wang
Jiuming Liang
Journal of Applied Polymer Science
Synergistic Reinforcement of Ethylene–Butene–Terpolymer Rubber by Graphene and Zinc Dimethacrylate: Multicrosslinking and Underlying Mechanisms Li Zhang Jianming Liu Duanjiao Li Wenxing Sun Zhi Li Yongchao Liang Qiang Fu Nian Tang Pengxiang Bai Yuqi Wang Jiuming Liang Journal of Applied Polymer Science ABSTRACTThe growing demand for advanced rubber composites highlights the need for enhanced performance and durability. This study explores the synergistic reinforcement effect of graphene nanosheets (GNs) and zinc dimethacrylate (ZDMA) on ethylene–butene–terpolymer (EBT) composites, focusing on their microscopic reinforcement mechanisms. In situ‐modified GNs and ZDMA are employed for co‐crosslinking. The impact of varying GNs contents and ZDMA ratios is analyzed, with a focus on their effects on the material's mechanical, thermal, and dynamic properties. GNs significantly enhance tensile strength, elongation at break, and hysteresis heat generation, while ZDMA further improves strength and thermal stability by optimizing the crosslinking network. Their synergy markedly boosts the performance of EBT composites, making them ideal for high‐strength, high‐temperature applications. The study provides design guidelines for advanced automotive rubber components and lays a foundation for optimizing EBT composites. 10.1002/app.57134 http://onlinelibrary.wiley.com/termsAndConditions#vor
title Synergistic Reinforcement of Ethylene–Butene–Terpolymer Rubber by Graphene and Zinc Dimethacrylate: Multicrosslinking and Underlying Mechanisms
topic Journal of Applied Polymer Science
url https://onlinelibrary.wiley.com/doi/10.1002/app.57134