Physicochemical, Radiation Shielding, and Anti‐Reflective Properties of PCL / PVC Nanocomposites Reinforced With Microwave‐Synthesized FeS 2 Nanospheres
Fuente:
Wiley Open Access
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Artículo Open Access |
| Published: |
Wiley
2025
|
| Subjects: | |
| Online Access: | |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1867013712047505408 |
|---|---|
| author | Sibel Selçuk Pekdemir Serpil Yalçin Kuzu Demet Yilmaz Mustafa Ersin Pekdemir Recep Taş Mediha Kök |
| author_facet | Sibel Selçuk Pekdemir Serpil Yalçin Kuzu Demet Yilmaz Mustafa Ersin Pekdemir Recep Taş Mediha Kök Sibel Selçuk Pekdemir Serpil Yalçin Kuzu Demet Yilmaz Mustafa Ersin Pekdemir Recep Taş Mediha Kök |
| collection | Wiley Open Access |
| contents | Physicochemical, Radiation Shielding, and Anti‐Reflective Properties of PCL / PVC Nanocomposites Reinforced With Microwave‐Synthesized FeS 2 Nanospheres Sibel Selçuk Pekdemir Serpil Yalçin Kuzu Demet Yilmaz Mustafa Ersin Pekdemir Recep Taş Mediha Kök Journal of Applied Polymer Science ABSTRACT In this study, poly ɛ‐caprolactone (PCL)/poly vinyl chloride (PVC) blend nanocomposite films reinforced with microwave‐assisted synthesized iron pyrite (FeS 2 ) nanospheres were obtained by the solvent casting method. Characterization of the composites was carried out using attenuated total reflectance‐Fourier transform infrared spectroscopy (ATR‐IR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), x‐ray diffraction (XRD), and scanning electron microscopy (SEM). Gamma‐ray shielding properties, including mass attenuation coefficients (MAC), mean free path (MFP), half‐value layer (HVL), and effective atomic numbers (Z eff ), were determined experimentally using a gamma spectrometer equipped with a ULEGe detector. The results indicate that increasing FeS 2 content enhances the gamma shielding performance, with PCL/PVC/10% FeS 2 exhibiting the highest attenuation capacity. Additionally, fast neutron shielding was evaluated through neutron equivalent dose measurements, confirming the potential of FeS 2 to improve neutron absorption. Theoretical calculations of exposure buildup factors (EBF), fast neutron removal cross‐section (ΣR), mass stopping power (MSP), and projected range (PR) were also computed. Furthermore, anti‐reflective properties were assessed by determining albedo parameters, revealing that FeS 2 effectively reduces gamma‐ray reflection by approximately 12.10%. The results suggest that FeS 2 doped PCL/PVC composites have significant potential for use in radiation shielding and anti‐reflective coatings in various industrial and biomedical applications. 10.1002/app.57737 http://onlinelibrary.wiley.com/termsAndConditions#vor |
| doi_str_mv | 10.1002/app.57737 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_app_57737 |
| institution | Wiley Open Access |
| license_str_mv | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| publishDate | 2025 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Physicochemical, Radiation Shielding, and Anti‐Reflective Properties of PCL / PVC Nanocomposites Reinforced With Microwave‐Synthesized FeS 2 Nanospheres Sibel Selçuk Pekdemir Serpil Yalçin Kuzu Demet Yilmaz Mustafa Ersin Pekdemir Recep Taş Mediha Kök Journal of Applied Polymer Science Physicochemical, Radiation Shielding, and Anti‐Reflective Properties of PCL / PVC Nanocomposites Reinforced With Microwave‐Synthesized FeS 2 Nanospheres Sibel Selçuk Pekdemir Serpil Yalçin Kuzu Demet Yilmaz Mustafa Ersin Pekdemir Recep Taş Mediha Kök Journal of Applied Polymer Science ABSTRACT In this study, poly ɛ‐caprolactone (PCL)/poly vinyl chloride (PVC) blend nanocomposite films reinforced with microwave‐assisted synthesized iron pyrite (FeS 2 ) nanospheres were obtained by the solvent casting method. Characterization of the composites was carried out using attenuated total reflectance‐Fourier transform infrared spectroscopy (ATR‐IR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), x‐ray diffraction (XRD), and scanning electron microscopy (SEM). Gamma‐ray shielding properties, including mass attenuation coefficients (MAC), mean free path (MFP), half‐value layer (HVL), and effective atomic numbers (Z eff ), were determined experimentally using a gamma spectrometer equipped with a ULEGe detector. The results indicate that increasing FeS 2 content enhances the gamma shielding performance, with PCL/PVC/10% FeS 2 exhibiting the highest attenuation capacity. Additionally, fast neutron shielding was evaluated through neutron equivalent dose measurements, confirming the potential of FeS 2 to improve neutron absorption. Theoretical calculations of exposure buildup factors (EBF), fast neutron removal cross‐section (ΣR), mass stopping power (MSP), and projected range (PR) were also computed. Furthermore, anti‐reflective properties were assessed by determining albedo parameters, revealing that FeS 2 effectively reduces gamma‐ray reflection by approximately 12.10%. The results suggest that FeS 2 doped PCL/PVC composites have significant potential for use in radiation shielding and anti‐reflective coatings in various industrial and biomedical applications. 10.1002/app.57737 http://onlinelibrary.wiley.com/termsAndConditions#vor |
| title | Physicochemical, Radiation Shielding, and Anti‐Reflective Properties of PCL / PVC Nanocomposites Reinforced With Microwave‐Synthesized FeS 2 Nanospheres |
| topic | Journal of Applied Polymer Science |
| url | https://onlinelibrary.wiley.com/doi/10.1002/app.57737 |