A “Turn‐On” Fluorescent Probe for the Visual Detection of Total Iron in Wine

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Main Authors: Ning Duan, Leyuan Ding, Shaoxiang Yang, Hongyu Tian, Baoguo Sun
Format: Artículo Open Access
Published: Wiley 2024
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author Ning Duan
Leyuan Ding
Shaoxiang Yang
Hongyu Tian
Baoguo Sun
author_facet Ning Duan
Leyuan Ding
Shaoxiang Yang
Hongyu Tian
Baoguo Sun
Ning Duan
Leyuan Ding
Shaoxiang Yang
Hongyu Tian
Baoguo Sun
collection Wiley Open Access
contents A “Turn‐On” Fluorescent Probe for the Visual Detection of Total Iron in Wine Ning Duan Leyuan Ding Shaoxiang Yang Hongyu Tian Baoguo Sun Luminescence ABSTRACTA turn‐on fluorescent sensor (E)‐4‐((4‐(5‐fluoro‐1H‐benzo[d]imidazol‐2‐yl)benzylidene)amino)phenol (FBAP) for the detection of Fe3+/2+ was synthesized. The fluorescence intensity of probe FBAP solution gradually increased with increased Fe3+ concentration. The low detection limit (LOD) was calculated to be 0.17 nM. The optimized structure and luminescent properties of FBAP were calculated by time‐dependent density functional theory (TD‐DFT) and Solvation Model Density (SMD). The rotation of the dihedral angle and ICT in the imine probe turned off the emission of the benzimidazole, which was restored upon cleaving the imine. Probe FBAP was successfully applied to determine whether Fe3+/2+ in wine exceeded the standard by phone and the rapid detection of Fe3+/2+ in the form of test strips was also conducted. 10.1002/bio.70021 http://onlinelibrary.wiley.com/termsAndConditions#vor
doi_str_mv 10.1002/bio.70021
format Artículo Open Access
id wiley_oa_10_1002_bio_70021
institution Wiley Open Access
license_str_mv http://onlinelibrary.wiley.com/termsAndConditions#vor
publishDate 2024
publisher Wiley
record_format wiley_oa
spellingShingle A “Turn‐On” Fluorescent Probe for the Visual Detection of Total Iron in Wine
Ning Duan
Leyuan Ding
Shaoxiang Yang
Hongyu Tian
Baoguo Sun
Luminescence
A “Turn‐On” Fluorescent Probe for the Visual Detection of Total Iron in Wine Ning Duan Leyuan Ding Shaoxiang Yang Hongyu Tian Baoguo Sun Luminescence ABSTRACTA turn‐on fluorescent sensor (E)‐4‐((4‐(5‐fluoro‐1H‐benzo[d]imidazol‐2‐yl)benzylidene)amino)phenol (FBAP) for the detection of Fe3+/2+ was synthesized. The fluorescence intensity of probe FBAP solution gradually increased with increased Fe3+ concentration. The low detection limit (LOD) was calculated to be 0.17 nM. The optimized structure and luminescent properties of FBAP were calculated by time‐dependent density functional theory (TD‐DFT) and Solvation Model Density (SMD). The rotation of the dihedral angle and ICT in the imine probe turned off the emission of the benzimidazole, which was restored upon cleaving the imine. Probe FBAP was successfully applied to determine whether Fe3+/2+ in wine exceeded the standard by phone and the rapid detection of Fe3+/2+ in the form of test strips was also conducted. 10.1002/bio.70021 http://onlinelibrary.wiley.com/termsAndConditions#vor
title A “Turn‐On” Fluorescent Probe for the Visual Detection of Total Iron in Wine
topic Luminescence
url https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/10.1002/bio.70021