Impact of Ring‐Closed Ratio on Properties of Benzoxazine via Solvent‐Free Continuous Flow Synthesis
Fuente:
Wiley Open Access
Enregistré dans:
| Auteurs principaux: | , , , , , |
|---|---|
| Format: | Artículo Open Access |
| Publié: |
Wiley
2025
|
| Sujets: | |
| Accès en ligne: | |
| Tags: |
Ajouter un tag
Pas de tags, Soyez le premier à ajouter un tag!
|
| _version_ | 1867005763972497408 |
|---|---|
| author | Changlu Zhou Sentao Lin Yuqiang Wang Tianxing Zhao Yuhang Tian Xianhao Gui |
| author_facet | Changlu Zhou Sentao Lin Yuqiang Wang Tianxing Zhao Yuhang Tian Xianhao Gui Changlu Zhou Sentao Lin Yuqiang Wang Tianxing Zhao Yuhang Tian Xianhao Gui |
| collection | Wiley Open Access |
| contents | Impact of Ring‐Closed Ratio on Properties of Benzoxazine via Solvent‐Free Continuous Flow Synthesis Changlu Zhou Sentao Lin Yuqiang Wang Tianxing Zhao Yuhang Tian Xianhao Gui Chemical Engineering & Technology AbstractA solvent‐free benzoxazine (Bz) synthesis process was established using continuous flow, utilizing p‐cresol, n‐butylamine, and an aqueous formaldehyde solution as raw materials to prepare Bz monomer of C‐ba. The optimization of process parameters resulted in a p‐cresol conversion of 93.5 % ± 1.1 %, a yield of 86.9 % ± 0.8 %, and a ring‐closed ratio (RCR) of 90.0 % ± 1.0 % under optimal conditions. The continuous flow process not only enhanced the RCR from 88.1 % to 90.0 % but also significantly reduced the reaction time by 96.7 % compared to traditional batch processes. Additionally, C‐ba with varying RCR values were investigated for their thermal properties, hydrophobicity, and antibacterial performance. 10.1002/ceat.70002 http://onlinelibrary.wiley.com/termsAndConditions#vor |
| doi_str_mv | 10.1002/ceat.70002 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_ceat_70002 |
| institution | Wiley Open Access |
| license_str_mv | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| publishDate | 2025 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Impact of Ring‐Closed Ratio on Properties of Benzoxazine via Solvent‐Free Continuous Flow Synthesis Changlu Zhou Sentao Lin Yuqiang Wang Tianxing Zhao Yuhang Tian Xianhao Gui Chemical Engineering & Technology Impact of Ring‐Closed Ratio on Properties of Benzoxazine via Solvent‐Free Continuous Flow Synthesis Changlu Zhou Sentao Lin Yuqiang Wang Tianxing Zhao Yuhang Tian Xianhao Gui Chemical Engineering & Technology AbstractA solvent‐free benzoxazine (Bz) synthesis process was established using continuous flow, utilizing p‐cresol, n‐butylamine, and an aqueous formaldehyde solution as raw materials to prepare Bz monomer of C‐ba. The optimization of process parameters resulted in a p‐cresol conversion of 93.5 % ± 1.1 %, a yield of 86.9 % ± 0.8 %, and a ring‐closed ratio (RCR) of 90.0 % ± 1.0 % under optimal conditions. The continuous flow process not only enhanced the RCR from 88.1 % to 90.0 % but also significantly reduced the reaction time by 96.7 % compared to traditional batch processes. Additionally, C‐ba with varying RCR values were investigated for their thermal properties, hydrophobicity, and antibacterial performance. 10.1002/ceat.70002 http://onlinelibrary.wiley.com/termsAndConditions#vor |
| title | Impact of Ring‐Closed Ratio on Properties of Benzoxazine via Solvent‐Free Continuous Flow Synthesis |
| topic | Chemical Engineering & Technology |
| url | https://onlinelibrary.wiley.com/doi/10.1002/ceat.70002 |