Homogeneous Catalyzed Direct Conversion of Furfural to Gamma‐Valerolactone

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Main Authors: Sakhitha Koranchalil, Danielle Lobo Justo Pinheiro, Rosa Padilla, Martin Nielsen
Format: Artículo Open Access
Published: Wiley 2024
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author Sakhitha Koranchalil
Danielle Lobo Justo Pinheiro
Rosa Padilla
Martin Nielsen
author_facet Sakhitha Koranchalil
Danielle Lobo Justo Pinheiro
Rosa Padilla
Martin Nielsen
Sakhitha Koranchalil
Danielle Lobo Justo Pinheiro
Rosa Padilla
Martin Nielsen
collection Wiley Open Access
contents Homogeneous Catalyzed Direct Conversion of Furfural to Gamma‐Valerolactone Sakhitha Koranchalil Danielle Lobo Justo Pinheiro Rosa Padilla Martin Nielsen ChemSusChem Abstract Herein, we report the direct conversion of biomass‐derived furfural to γ‐valerolactone (GVL) in a one‐pot system, using the combination of Ru‐MACHO‐BH and a Brønsted acid (H 3 PO 4 ). A GVL yield of 84 % is achieved under mild reaction conditions using 1 mol% of Ru‐MACHO‐BH and 3.8 M H 3 PO 4 (aq) at 100 °C for 7 hours. 10.1002/cssc.202301608 http://creativecommons.org/licenses/by-nc/4.0/
doi_str_mv 10.1002/cssc.202301608
format Artículo Open Access
id wiley_oa_10_1002_cssc_202301608
institution Wiley Open Access
license_str_mv http://creativecommons.org/licenses/by-nc/4.0/
publishDate 2024
publisher Wiley
record_format wiley_oa
spellingShingle Homogeneous Catalyzed Direct Conversion of Furfural to Gamma‐Valerolactone
Sakhitha Koranchalil
Danielle Lobo Justo Pinheiro
Rosa Padilla
Martin Nielsen
ChemSusChem
Homogeneous Catalyzed Direct Conversion of Furfural to Gamma‐Valerolactone Sakhitha Koranchalil Danielle Lobo Justo Pinheiro Rosa Padilla Martin Nielsen ChemSusChem Abstract Herein, we report the direct conversion of biomass‐derived furfural to γ‐valerolactone (GVL) in a one‐pot system, using the combination of Ru‐MACHO‐BH and a Brønsted acid (H 3 PO 4 ). A GVL yield of 84 % is achieved under mild reaction conditions using 1 mol% of Ru‐MACHO‐BH and 3.8 M H 3 PO 4 (aq) at 100 °C for 7 hours. 10.1002/cssc.202301608 http://creativecommons.org/licenses/by-nc/4.0/
title Homogeneous Catalyzed Direct Conversion of Furfural to Gamma‐Valerolactone
topic ChemSusChem
url https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202301608