Azolium‐Porphyrin Electrosynthesis
Fuente:
Wiley Open Access
Guardado en:
| Autores principales: | , , , , , , , , , , , |
|---|---|
| Formato: | Artículo Open Access |
| Publicado: |
Wiley
2024
|
| Materias: | |
| Acceso en línea: | |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| _version_ | 1867008508669460481 |
|---|---|
| author | Fatima Akhssas Rongning Lin Michal Trojan Ludivine Poyac Nesrine Amiri Thibault Ertel Sophie Fournier Emmanuel Lerayer Hélène Cattey Sébastien Clément Sébastien Richeter Charles H. Devillers |
| author_facet | Fatima Akhssas Rongning Lin Michal Trojan Ludivine Poyac Nesrine Amiri Thibault Ertel Sophie Fournier Emmanuel Lerayer Hélène Cattey Sébastien Clément Sébastien Richeter Charles H. Devillers Fatima Akhssas Rongning Lin Michal Trojan Ludivine Poyac Nesrine Amiri Thibault Ertel Sophie Fournier Emmanuel Lerayer Hélène Cattey Sébastien Clément Sébastien Richeter Charles H. Devillers |
| collection | Wiley Open Access |
| contents | Azolium‐Porphyrin Electrosynthesis Fatima Akhssas Rongning Lin Michal Trojan Ludivine Poyac Nesrine Amiri Thibault Ertel Sophie Fournier Emmanuel Lerayer Hélène Cattey Sébastien Clément Sébastien Richeter Charles H. Devillers ChemSusChem AbstractElectrochemical oxidation of Zn(II) 2,7,12,17‐tetra‐tert‐butylporphyrin in the presence of a series of azole derivatives (1‐methylimidazole, 1‐vinyl‐1H‐imidazole, 2‐(1H‐imidazol‐1‐yl)pyridine, 1‐methylbenzimidazole, 1‐methyl‐1H‐1,2,4‐triazole, and benzothiazole) affords the corresponding meso‐substituted azolium‐porphyrins in very mild conditions and good yields. It was found that these nucleophiles were strongly ligated to the zinc(II) azolium‐porphyrin complexes. Thus a demetalation/remetalation procedure was performed to recover the non‐azole‐coordinated zinc(II) complexes. X‐ray crystallographic structures of three azolium‐porphyrins were solved. Cyclic voltammetry analyses provided insight into the electron‐withdrawing effect of the azolium substituents. 10.1002/cssc.202401439 http://creativecommons.org/licenses/by/4.0/ |
| doi_str_mv | 10.1002/cssc.202401439 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_cssc_202401439 |
| institution | Wiley Open Access |
| license_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| publishDate | 2024 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Azolium‐Porphyrin Electrosynthesis Fatima Akhssas Rongning Lin Michal Trojan Ludivine Poyac Nesrine Amiri Thibault Ertel Sophie Fournier Emmanuel Lerayer Hélène Cattey Sébastien Clément Sébastien Richeter Charles H. Devillers ChemSusChem Azolium‐Porphyrin Electrosynthesis Fatima Akhssas Rongning Lin Michal Trojan Ludivine Poyac Nesrine Amiri Thibault Ertel Sophie Fournier Emmanuel Lerayer Hélène Cattey Sébastien Clément Sébastien Richeter Charles H. Devillers ChemSusChem AbstractElectrochemical oxidation of Zn(II) 2,7,12,17‐tetra‐tert‐butylporphyrin in the presence of a series of azole derivatives (1‐methylimidazole, 1‐vinyl‐1H‐imidazole, 2‐(1H‐imidazol‐1‐yl)pyridine, 1‐methylbenzimidazole, 1‐methyl‐1H‐1,2,4‐triazole, and benzothiazole) affords the corresponding meso‐substituted azolium‐porphyrins in very mild conditions and good yields. It was found that these nucleophiles were strongly ligated to the zinc(II) azolium‐porphyrin complexes. Thus a demetalation/remetalation procedure was performed to recover the non‐azole‐coordinated zinc(II) complexes. X‐ray crystallographic structures of three azolium‐porphyrins were solved. Cyclic voltammetry analyses provided insight into the electron‐withdrawing effect of the azolium substituents. 10.1002/cssc.202401439 http://creativecommons.org/licenses/by/4.0/ |
| title | Azolium‐Porphyrin Electrosynthesis |
| topic | ChemSusChem |
| url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202401439 |