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| Main Authors: | , , , |
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| Format: | Artículo Open Access |
| Published: |
Wiley
2025
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| Subjects: | |
| Online Access: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202500155 |
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Table of Contents:
- Selectively Electrochemical Reduction of CO2 Based on Metal Clusters Catalysts Xiaoxia Zhou Guohui Li Chenghong Zhang XiangZhi Cui ChemSusChem The electrochemical CO2 reduction reaction (eCO2RR) has emerged as a pivotal technology for addressing global climate challenges by converting CO2 into value‐added chemicals, thereby contributing to carbon neutrality efforts. Metal nanoclusters, characterized by their atomically precise structures and unique electronic properties, have gained significant attention as highly tunable catalysts for eCO2RR due to their exceptional activity and selectivity. This review systematically summarizes recent advancements in metal nanoclusters for CO2 conversion. First, the fundamental reaction mechanisms and pathways governing the formation of key products such as CO, formic acid, and hydrocarbons are elucidated. Next, the catalysts involved in eCO2RR, including noble metal (e.g., Au, Ag) and non‐noble metal (e.g., Cu, Ni) clusters are summarized, and the latest technical strategies for enhancing CO2 reduction efficiency, such as alloying, ligand engineering, defect engineering, and heteroatom doping are presented. Finally, the challenges of metal nanoclusters in eCO2RR are discussed and future research directions and development prospects are outlined. This review puts forward the cutting‐edge design strategy of atomic‐level precise metal nanocluster catalysts in eCO2RR, which not only deepens the understanding of the basic science of electrocatalysis but also provides a feasible technical roadmap for realizing a sustainable CO2 circular economy. 10.1002/cssc.202500155 http://onlinelibrary.wiley.com/termsAndConditions#vor