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| Auteurs principaux: | , , , , , , , , |
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| Format: | Artículo Open Access |
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Wiley
2025
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| Accès en ligne: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202500953 |
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| _version_ | 1867015907192078337 |
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| author | Junhao Huang Marcus Klahn Stephan Bartling Anna Zimina Nils Rockstroh Norbert Steinfeldt Tim Peppel Jan‐Dierk Grunwaldt Jennifer Strunk |
| author_facet | Junhao Huang Marcus Klahn Stephan Bartling Anna Zimina Nils Rockstroh Norbert Steinfeldt Tim Peppel Jan‐Dierk Grunwaldt Jennifer Strunk Junhao Huang Marcus Klahn Stephan Bartling Anna Zimina Nils Rockstroh Norbert Steinfeldt Tim Peppel Jan‐Dierk Grunwaldt Jennifer Strunk |
| collection | Wiley Open Access |
| contents | Atomically Dispersed Palladium Promoted Suzuki–Miyaura Cross Coupling Junhao Huang Marcus Klahn Stephan Bartling Anna Zimina Nils Rockstroh Norbert Steinfeldt Tim Peppel Jan‐Dierk Grunwaldt Jennifer Strunk ChemSusChem The palladium‐catalyzed Suzuki – Miyaura cross coupling reaction to forge carbon‐carbon bonds fundamentally changes the practice of organic synthesis. Herein an isolated palladium catalyst supported on polymeric carbon nitride (Pd/PCN) for efficient cross coupling of bromobenzene and phenylboronic acid at room temperature is reported. It is demonstrated that the Pd/PCN catalyst with a 2 wt% Pd loading achieves the highest mole‐specific activity. In addition, the size of supported Pd can strongly affect the reaction performance: the isolated Pd species exhibit higher activity compared to the Pd nanoparticles. The continuous flow tests demonstrate that the catalytic properties of the Pd/PCN catalyst strongly depend on the reaction atmosphere: Pd‐catalyzed self‐coupling of phenylboronic acid as a side reaction is more pronounced under an O 2 flow than in an Ar flow. Detailed mechanistic investigations through in situ infrared spectroscopy reveal the role of the base K 2 CO 3 in activating the phenylboronic acid. 10.1002/cssc.202500953 http://creativecommons.org/licenses/by/4.0/ |
| doi_str_mv | 10.1002/cssc.202500953 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_cssc_202500953 |
| institution | Wiley Open Access |
| license_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| publishDate | 2025 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Atomically Dispersed Palladium Promoted Suzuki–Miyaura Cross Coupling Junhao Huang Marcus Klahn Stephan Bartling Anna Zimina Nils Rockstroh Norbert Steinfeldt Tim Peppel Jan‐Dierk Grunwaldt Jennifer Strunk ChemSusChem Atomically Dispersed Palladium Promoted Suzuki–Miyaura Cross Coupling Junhao Huang Marcus Klahn Stephan Bartling Anna Zimina Nils Rockstroh Norbert Steinfeldt Tim Peppel Jan‐Dierk Grunwaldt Jennifer Strunk ChemSusChem The palladium‐catalyzed Suzuki – Miyaura cross coupling reaction to forge carbon‐carbon bonds fundamentally changes the practice of organic synthesis. Herein an isolated palladium catalyst supported on polymeric carbon nitride (Pd/PCN) for efficient cross coupling of bromobenzene and phenylboronic acid at room temperature is reported. It is demonstrated that the Pd/PCN catalyst with a 2 wt% Pd loading achieves the highest mole‐specific activity. In addition, the size of supported Pd can strongly affect the reaction performance: the isolated Pd species exhibit higher activity compared to the Pd nanoparticles. The continuous flow tests demonstrate that the catalytic properties of the Pd/PCN catalyst strongly depend on the reaction atmosphere: Pd‐catalyzed self‐coupling of phenylboronic acid as a side reaction is more pronounced under an O 2 flow than in an Ar flow. Detailed mechanistic investigations through in situ infrared spectroscopy reveal the role of the base K 2 CO 3 in activating the phenylboronic acid. 10.1002/cssc.202500953 http://creativecommons.org/licenses/by/4.0/ |
| title | Atomically Dispersed Palladium Promoted Suzuki–Miyaura Cross Coupling |
| topic | ChemSusChem |
| url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202500953 |