Thiophene‐Derived Porous Organic Semiconductors as Promising Photocatalysts for Green H 2 O 2 Synthesis: Structure–Performance Relationships, Current Challenges, and Perspectives
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| Formato: | Artículo Open Access |
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Wiley
2025
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| _version_ | 1867011191754194944 |
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| author | He Wang Xin Tao |
| author_facet | He Wang Xin Tao He Wang Xin Tao |
| collection | Wiley Open Access |
| contents | Thiophene‐Derived Porous Organic Semiconductors as Promising Photocatalysts for Green H 2 O 2 Synthesis: Structure–Performance Relationships, Current Challenges, and Perspectives He Wang Xin Tao ChemSusChem Artificial photosynthesis using earth abundant resources water and oxygen to give a green oxidant hydrogen peroxide (H 2 O 2 ) has drawn extensive attention. Targeted designing photocatalysts for efficient H 2 O 2 synthesis remains a fundamental and technological challenge. In this regard, thiophene‐derived structural motifs with unique conjugation systems and electron‐rich properties often serve as building blocks for synthesis of metal‐free porous organic semiconductors (POSs). These semiconductors have advantages for instance broad light absorption range, efficient charge separation and transfer, superior mass transportation, and good stability, along with flexible synthesis and functionalization, which exhibit excellent performance in H 2 O 2 photosynthesis. This review summarizes the recent key advances in the synthesis of thiophene‐derived POSs and their applications for H 2 O 2 synthesis, which poses the current bottlenecks in this area. A general perspective on the future effort on this topic is provided. 10.1002/cssc.202502213 http://onlinelibrary.wiley.com/termsAndConditions#vor |
| doi_str_mv | 10.1002/cssc.202502213 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_cssc_202502213 |
| institution | Wiley Open Access |
| license_str_mv | http://onlinelibrary.wiley.com/termsAndConditions#vor |
| publishDate | 2025 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Thiophene‐Derived Porous Organic Semiconductors as Promising Photocatalysts for Green H 2 O 2 Synthesis: Structure–Performance Relationships, Current Challenges, and Perspectives He Wang Xin Tao ChemSusChem Thiophene‐Derived Porous Organic Semiconductors as Promising Photocatalysts for Green H 2 O 2 Synthesis: Structure–Performance Relationships, Current Challenges, and Perspectives He Wang Xin Tao ChemSusChem Artificial photosynthesis using earth abundant resources water and oxygen to give a green oxidant hydrogen peroxide (H 2 O 2 ) has drawn extensive attention. Targeted designing photocatalysts for efficient H 2 O 2 synthesis remains a fundamental and technological challenge. In this regard, thiophene‐derived structural motifs with unique conjugation systems and electron‐rich properties often serve as building blocks for synthesis of metal‐free porous organic semiconductors (POSs). These semiconductors have advantages for instance broad light absorption range, efficient charge separation and transfer, superior mass transportation, and good stability, along with flexible synthesis and functionalization, which exhibit excellent performance in H 2 O 2 photosynthesis. This review summarizes the recent key advances in the synthesis of thiophene‐derived POSs and their applications for H 2 O 2 synthesis, which poses the current bottlenecks in this area. A general perspective on the future effort on this topic is provided. 10.1002/cssc.202502213 http://onlinelibrary.wiley.com/termsAndConditions#vor |
| title | Thiophene‐Derived Porous Organic Semiconductors as Promising Photocatalysts for Green H 2 O 2 Synthesis: Structure–Performance Relationships, Current Challenges, and Perspectives |
| topic | ChemSusChem |
| url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.202502213 |