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| Natura: | Artículo Open Access |
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Wiley
2026
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| Accesso online: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.70609 |
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| _version_ | 1867008060087599104 |
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| author | Attila R. Herczegh Péter R. Kollár Johannes Lehmann Zoltán Novák |
| author_facet | Attila R. Herczegh Péter R. Kollár Johannes Lehmann Zoltán Novák Attila R. Herczegh Péter R. Kollár Johannes Lehmann Zoltán Novák |
| collection | Wiley Open Access |
| contents | Development of Mild Palladium‐Catalyzed N‐Arylation of Ortho‐Acylanilines in Rhamnolipid Micellar System Attila R. Herczegh Péter R. Kollár Johannes Lehmann Zoltán Novák ChemSusChem We developed a green and efficient method for Pd‐catalyzed N‐arylation of ortho‐acylanilines in water using rhamnolipid‐based micellar catalysis. The (cinnamylPdCl) 2 / t BuXPhos system enables high yields at 40°C, significantly lower than conventional methods (>100°C), with broad substrate scope. This industrially produced biodegradable surfactant system offers a sustainable alternative to organic solvents, combining enhanced reactivity with improved energy efficiency and environmental compatibility. 10.1002/cssc.70609 http://creativecommons.org/licenses/by/4.0/ |
| doi_str_mv | 10.1002/cssc.70609 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_cssc_70609 |
| institution | Wiley Open Access |
| license_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| publishDate | 2026 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Development of Mild Palladium‐Catalyzed N‐Arylation of Ortho‐Acylanilines in Rhamnolipid Micellar System Attila R. Herczegh Péter R. Kollár Johannes Lehmann Zoltán Novák ChemSusChem Development of Mild Palladium‐Catalyzed N‐Arylation of Ortho‐Acylanilines in Rhamnolipid Micellar System Attila R. Herczegh Péter R. Kollár Johannes Lehmann Zoltán Novák ChemSusChem We developed a green and efficient method for Pd‐catalyzed N‐arylation of ortho‐acylanilines in water using rhamnolipid‐based micellar catalysis. The (cinnamylPdCl) 2 / t BuXPhos system enables high yields at 40°C, significantly lower than conventional methods (>100°C), with broad substrate scope. This industrially produced biodegradable surfactant system offers a sustainable alternative to organic solvents, combining enhanced reactivity with improved energy efficiency and environmental compatibility. 10.1002/cssc.70609 http://creativecommons.org/licenses/by/4.0/ |
| title | Development of Mild Palladium‐Catalyzed N‐Arylation of Ortho‐Acylanilines in Rhamnolipid Micellar System |
| topic | ChemSusChem |
| url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/cssc.70609 |