Advanced Current Collector Design for High Energy Density Anode‐Free Sodium‐Ion Batteries

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Main Authors: Zhenzhu Wang, Jia Song, Xiaofeng Li, ChaoZhong Liu, Meijuan Liu, Lizhi Li, Xiaoyu Xu, Yumei Wang, Jiangfeng Ni, Bo Song
Format: Artículo Open Access
Published: Wiley 2025
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author Zhenzhu Wang
Jia Song
Xiaofeng Li
ChaoZhong Liu
Meijuan Liu
Lizhi Li
Xiaoyu Xu
Yumei Wang
Jiangfeng Ni
Bo Song
author_facet Zhenzhu Wang
Jia Song
Xiaofeng Li
ChaoZhong Liu
Meijuan Liu
Lizhi Li
Xiaoyu Xu
Yumei Wang
Jiangfeng Ni
Bo Song
Zhenzhu Wang
Jia Song
Xiaofeng Li
ChaoZhong Liu
Meijuan Liu
Lizhi Li
Xiaoyu Xu
Yumei Wang
Jiangfeng Ni
Bo Song
collection Wiley Open Access
contents Advanced Current Collector Design for High Energy Density Anode‐Free Sodium‐Ion Batteries Zhenzhu Wang Jia Song Xiaofeng Li ChaoZhong Liu Meijuan Liu Lizhi Li Xiaoyu Xu Yumei Wang Jiangfeng Ni Bo Song Electron ABSTRACT Anode‐free sodium‐ion batteries (AFSIBs) achieve energy storage by completely eliminating traditional anode active materials and relying solely on the reversible plating and stripping of sodium from the anode source onto the current collector surface. This approach fundamentally addresses the limitations of energy density and safety inherent in conventional sodium batteries, positioning it as a promising candidate for high‐energy “super‐lithium” electrochemical storage technology. However, this innovative design also places unprecedentedly stringent demands on the current collector, making it a critical component in determining cell performance. This review systematically outlines the prevailing methodologies and research progress on modifying collectors for AFSIBs, with a focus on material sodophilicity engineering and structural modulation. By comprehensively reviewing the process of different sodium‐friendly material modifications, interfacial functional modulation, porous structure configuration, and gradient engineering on the cell performance, the essential elements for enhancing the electrochemical performance of the current collector are outlined. Building on this, the paper discusses the challenges and opportunities in this field and suggests new research directions for developing high‐performance AFSIBs. 10.1002/elt2.70013 http://creativecommons.org/licenses/by/4.0/
doi_str_mv 10.1002/elt2.70013
format Artículo Open Access
id wiley_oa_10_1002_elt2_70013
institution Wiley Open Access
license_str_mv http://creativecommons.org/licenses/by/4.0/
publishDate 2025
publisher Wiley
record_format wiley_oa
spellingShingle Advanced Current Collector Design for High Energy Density Anode‐Free Sodium‐Ion Batteries
Zhenzhu Wang
Jia Song
Xiaofeng Li
ChaoZhong Liu
Meijuan Liu
Lizhi Li
Xiaoyu Xu
Yumei Wang
Jiangfeng Ni
Bo Song
Electron
Advanced Current Collector Design for High Energy Density Anode‐Free Sodium‐Ion Batteries Zhenzhu Wang Jia Song Xiaofeng Li ChaoZhong Liu Meijuan Liu Lizhi Li Xiaoyu Xu Yumei Wang Jiangfeng Ni Bo Song Electron ABSTRACT Anode‐free sodium‐ion batteries (AFSIBs) achieve energy storage by completely eliminating traditional anode active materials and relying solely on the reversible plating and stripping of sodium from the anode source onto the current collector surface. This approach fundamentally addresses the limitations of energy density and safety inherent in conventional sodium batteries, positioning it as a promising candidate for high‐energy “super‐lithium” electrochemical storage technology. However, this innovative design also places unprecedentedly stringent demands on the current collector, making it a critical component in determining cell performance. This review systematically outlines the prevailing methodologies and research progress on modifying collectors for AFSIBs, with a focus on material sodophilicity engineering and structural modulation. By comprehensively reviewing the process of different sodium‐friendly material modifications, interfacial functional modulation, porous structure configuration, and gradient engineering on the cell performance, the essential elements for enhancing the electrochemical performance of the current collector are outlined. Building on this, the paper discusses the challenges and opportunities in this field and suggests new research directions for developing high‐performance AFSIBs. 10.1002/elt2.70013 http://creativecommons.org/licenses/by/4.0/
title Advanced Current Collector Design for High Energy Density Anode‐Free Sodium‐Ion Batteries
topic Electron
url https://onlinelibrary.wiley.com/doi/10.1002/elt2.70013