Influence of sodium benzoate on key colloid properties of sodium lauryl ether sulfate: Identification of a possible interfacial structure decoupler

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Hauptverfasser: Ericson Mata‐Zabala, Luz Margarita Rattia Bravo, Álvaro Javier Patiño‐Agudelo, Lucas Santos Silva, Nelson Barrios, Juan Pereira
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Veröffentlicht: Wiley 2025
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author Ericson Mata‐Zabala
Luz Margarita Rattia Bravo
Álvaro Javier Patiño‐Agudelo
Lucas Santos Silva
Nelson Barrios
Juan Pereira
author_facet Ericson Mata‐Zabala
Luz Margarita Rattia Bravo
Álvaro Javier Patiño‐Agudelo
Lucas Santos Silva
Nelson Barrios
Juan Pereira
Ericson Mata‐Zabala
Luz Margarita Rattia Bravo
Álvaro Javier Patiño‐Agudelo
Lucas Santos Silva
Nelson Barrios
Juan Pereira
collection Wiley Open Access
contents Influence of sodium benzoate on key colloid properties of sodium lauryl ether sulfate: Identification of a possible interfacial structure decoupler Ericson Mata‐Zabala Luz Margarita Rattia Bravo Álvaro Javier Patiño‐Agudelo Lucas Santos Silva Nelson Barrios Juan Pereira Journal of Surfactants and Detergents AbstractSurfactant–oil–water (SOW) systems, particularly when packaged in metal containers, require chemical reagents with preservative and anticorrosive properties. This study aims to investigate the influence of sodium benzoate (NaBz) on fundamental interfacial properties of the surfactant lauryl ether sulfate (SLES) with two ethoxylation units (EO = 2). Using a combination of surface tension, electrical conductivity, and isothermal titration calorimetry (ITC) measurements, we evaluated SLES systems in the presence of NaCl, NaBz, and various mixtures of these salts using salinity scans, at room temperature. NaBz inhibits the formation of triphasic system in SOW formulation. The thermodynamic stability of SLES micelles followed the order: with entropy being the primary driving force. The results suggest that NaBz acts as a potential interfacial structure decoupler. This novel behavior of NaBz may have important implications for its use in SOW systems, particularly in formulations requiring stability and integrity in aggregation state. 10.1002/jsde.12839 http://onlinelibrary.wiley.com/termsAndConditions#vor
doi_str_mv 10.1002/jsde.12839
format Artículo Open Access
id wiley_oa_10_1002_jsde_12839
institution Wiley Open Access
license_str_mv http://onlinelibrary.wiley.com/termsAndConditions#vor
publishDate 2025
publisher Wiley
record_format wiley_oa
spellingShingle Influence of sodium benzoate on key colloid properties of sodium lauryl ether sulfate: Identification of a possible interfacial structure decoupler
Ericson Mata‐Zabala
Luz Margarita Rattia Bravo
Álvaro Javier Patiño‐Agudelo
Lucas Santos Silva
Nelson Barrios
Juan Pereira
Journal of Surfactants and Detergents
Influence of sodium benzoate on key colloid properties of sodium lauryl ether sulfate: Identification of a possible interfacial structure decoupler Ericson Mata‐Zabala Luz Margarita Rattia Bravo Álvaro Javier Patiño‐Agudelo Lucas Santos Silva Nelson Barrios Juan Pereira Journal of Surfactants and Detergents AbstractSurfactant–oil–water (SOW) systems, particularly when packaged in metal containers, require chemical reagents with preservative and anticorrosive properties. This study aims to investigate the influence of sodium benzoate (NaBz) on fundamental interfacial properties of the surfactant lauryl ether sulfate (SLES) with two ethoxylation units (EO = 2). Using a combination of surface tension, electrical conductivity, and isothermal titration calorimetry (ITC) measurements, we evaluated SLES systems in the presence of NaCl, NaBz, and various mixtures of these salts using salinity scans, at room temperature. NaBz inhibits the formation of triphasic system in SOW formulation. The thermodynamic stability of SLES micelles followed the order: with entropy being the primary driving force. The results suggest that NaBz acts as a potential interfacial structure decoupler. This novel behavior of NaBz may have important implications for its use in SOW systems, particularly in formulations requiring stability and integrity in aggregation state. 10.1002/jsde.12839 http://onlinelibrary.wiley.com/termsAndConditions#vor
title Influence of sodium benzoate on key colloid properties of sodium lauryl ether sulfate: Identification of a possible interfacial structure decoupler
topic Journal of Surfactants and Detergents
url https://aocs.onlinelibrary.wiley.com/doi/10.1002/jsde.12839