Aerosol Assisted Chemical Vapour Deposition (AACVD) of Zinc dichalcogenoimidodiphosphinate Complexes for the Deposition of Zinc Selenide Thin Films
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| Format: | Artículo Open Access |
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2024
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| author | Temidayo Oyetunde Martins O. Omorogie Paul O'Brien |
| author_facet | Temidayo Oyetunde Martins O. Omorogie Paul O'Brien Temidayo Oyetunde Martins O. Omorogie Paul O'Brien |
| collection | Wiley Open Access |
| contents | Aerosol Assisted Chemical Vapour Deposition (AACVD) of Zinc dichalcogenoimidodiphosphinate Complexes for the Deposition of Zinc Selenide Thin Films Temidayo Oyetunde Martins O. Omorogie Paul O'Brien ChemistryOpen Abstract Dichalcogenoimidodiphosphinate complexes of zinc [Zn{(EP i Pr 2 ) 2 N} 2 ], [E=Se,Se; S,Se] were synthesized through metathetical reactions from the dichalcogenoimidodiphosphinate ligands [(EE'P i Pr 2 NH)] (E, E’=Se, Se; S, Se). These complexes were characterized and used as single‐source precursors through Aerosol‐Assisted Chemical Vapour Deposition (AACVD) for the deposition of cubic zinc selenide (ZnSe) films on glass substrates. The deposition temperature occurred at 500 and 525 °C, while the flow rates of the carrier gas was 160 and 240 standard cubic centimetre (sccm). The morphology of the deposited films ranged between dense fibrous network and woven fibres. X‐ray photoelectron spectroscopy (XPS) confirmed the presence of the constituent elements in zinc selenide. 10.1002/open.202400295 http://creativecommons.org/licenses/by/4.0/ |
| doi_str_mv | 10.1002/open.202400295 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_open_202400295 |
| institution | Wiley Open Access |
| license_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| publishDate | 2024 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Aerosol Assisted Chemical Vapour Deposition (AACVD) of Zinc dichalcogenoimidodiphosphinate Complexes for the Deposition of Zinc Selenide Thin Films Temidayo Oyetunde Martins O. Omorogie Paul O'Brien ChemistryOpen Aerosol Assisted Chemical Vapour Deposition (AACVD) of Zinc dichalcogenoimidodiphosphinate Complexes for the Deposition of Zinc Selenide Thin Films Temidayo Oyetunde Martins O. Omorogie Paul O'Brien ChemistryOpen Abstract Dichalcogenoimidodiphosphinate complexes of zinc [Zn{(EP i Pr 2 ) 2 N} 2 ], [E=Se,Se; S,Se] were synthesized through metathetical reactions from the dichalcogenoimidodiphosphinate ligands [(EE'P i Pr 2 NH)] (E, E’=Se, Se; S, Se). These complexes were characterized and used as single‐source precursors through Aerosol‐Assisted Chemical Vapour Deposition (AACVD) for the deposition of cubic zinc selenide (ZnSe) films on glass substrates. The deposition temperature occurred at 500 and 525 °C, while the flow rates of the carrier gas was 160 and 240 standard cubic centimetre (sccm). The morphology of the deposited films ranged between dense fibrous network and woven fibres. X‐ray photoelectron spectroscopy (XPS) confirmed the presence of the constituent elements in zinc selenide. 10.1002/open.202400295 http://creativecommons.org/licenses/by/4.0/ |
| title | Aerosol Assisted Chemical Vapour Deposition (AACVD) of Zinc dichalcogenoimidodiphosphinate Complexes for the Deposition of Zinc Selenide Thin Films |
| topic | ChemistryOpen |
| url | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/open.202400295 |