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| Main Authors: | , , |
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| Format: | Artículo Open Access |
| Published: |
Wiley
2025
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| Subjects: | |
| Online Access: | https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/open.202400513 |
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Table of Contents:
- Silver‐Catalyzed Decarboxylative Coupling of Oxamic Acids with Styrenes to Synthesize E ‐Cinnamamides: A Distinguish Reaction Pathway Ru‐Han A Yong‐Wang Huo Xiao‐Feng Wu ChemistryOpen Abstract A silver‐catalyzed decarboxylative coupling of oxamic acids with styrenes has been developed to produce E ‐cinnamamides. Oxamic acids act as efficient precursors for carbamoy radicals. Based on the mechanistic experiments and intermediate analysis, the proposed mechanism involves radical addition to styrenes, followed by oxidation and solvent participation, ultimately leading to the formation of cinnamamides which is different from the reported cases. 10.1002/open.202400513 http://creativecommons.org/licenses/by/4.0/