Porous CeO 2 /CuO Heterostructure for Efficient Hydrogen Evolution Reaction in an Acidic Medium

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Autori principali: Binod Raj KC, Samira Munkaila, Bishnu Prasad Bastakoti
Natura: Artículo Open Access
Pubblicazione: Wiley 2025
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author Binod Raj KC
Samira Munkaila
Bishnu Prasad Bastakoti
author_facet Binod Raj KC
Samira Munkaila
Bishnu Prasad Bastakoti
Binod Raj KC
Samira Munkaila
Bishnu Prasad Bastakoti
collection Wiley Open Access
contents Porous CeO 2 /CuO Heterostructure for Efficient Hydrogen Evolution Reaction in an Acidic Medium Binod Raj KC Samira Munkaila Bishnu Prasad Bastakoti ChemistryOpen A composite electrocatalyst CeO 2 /CuO is fabricated for the hydrogen evolution reaction (HER) via a simple, facile, one‐step hydrothermal method, using F‐127 as a template and structure directing agent. The prepared composite CeO 2 /CuO shows top‐notch HER activities with a small overpotential of 98 mV at 10 mA cm −2 and just 160 mV overpotential to attain a current density of 50 mA cm −2 with good stability for 20 h in an acidic medium. The enhanced catalytic activities of CeO 2 /CuO nanocomposite are attributed to their synergetic interface interaction, which lead to improved conductivity, reactive sites, and oxygen vacancies in their lattices. This study aims to advance the development of earth‐abundant transition metal oxides–based electrocatalysts as economical, durable, and efficient HER electrocatalysts to replace noble metal–based materials in the future. 10.1002/open.202500115 http://creativecommons.org/licenses/by/4.0/
doi_str_mv 10.1002/open.202500115
format Artículo Open Access
id wiley_oa_10_1002_open_202500115
institution Wiley Open Access
license_str_mv http://creativecommons.org/licenses/by/4.0/
publishDate 2025
publisher Wiley
record_format wiley_oa
spellingShingle Porous CeO 2 /CuO Heterostructure for Efficient Hydrogen Evolution Reaction in an Acidic Medium
Binod Raj KC
Samira Munkaila
Bishnu Prasad Bastakoti
ChemistryOpen
Porous CeO 2 /CuO Heterostructure for Efficient Hydrogen Evolution Reaction in an Acidic Medium Binod Raj KC Samira Munkaila Bishnu Prasad Bastakoti ChemistryOpen A composite electrocatalyst CeO 2 /CuO is fabricated for the hydrogen evolution reaction (HER) via a simple, facile, one‐step hydrothermal method, using F‐127 as a template and structure directing agent. The prepared composite CeO 2 /CuO shows top‐notch HER activities with a small overpotential of 98 mV at 10 mA cm −2 and just 160 mV overpotential to attain a current density of 50 mA cm −2 with good stability for 20 h in an acidic medium. The enhanced catalytic activities of CeO 2 /CuO nanocomposite are attributed to their synergetic interface interaction, which lead to improved conductivity, reactive sites, and oxygen vacancies in their lattices. This study aims to advance the development of earth‐abundant transition metal oxides–based electrocatalysts as economical, durable, and efficient HER electrocatalysts to replace noble metal–based materials in the future. 10.1002/open.202500115 http://creativecommons.org/licenses/by/4.0/
title Porous CeO 2 /CuO Heterostructure for Efficient Hydrogen Evolution Reaction in an Acidic Medium
topic ChemistryOpen
url https://chemistry-europe.onlinelibrary.wiley.com/doi/10.1002/open.202500115