Remarkably Enhancing the Bonding Performance of Aluminum Alloy/ CFRE Hybrid Joints by Directionally Inducing Covalent Bonds and Mechanical Interlocking via Shark Scale Structures and Silane‐Functionalized Interfaces

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Main Authors: Si Zhang, Nuoyi Wu, Chuanbo An, Zhiying Sun, Xu Li, Fuying Zhao, Xiaoxue Wang, Yun Chen
Format: Artículo Open Access
Published: Wiley 2026
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author Si Zhang
Nuoyi Wu
Chuanbo An
Zhiying Sun
Xu Li
Fuying Zhao
Xiaoxue Wang
Yun Chen
author_facet Si Zhang
Nuoyi Wu
Chuanbo An
Zhiying Sun
Xu Li
Fuying Zhao
Xiaoxue Wang
Yun Chen
Si Zhang
Nuoyi Wu
Chuanbo An
Zhiying Sun
Xu Li
Fuying Zhao
Xiaoxue Wang
Yun Chen
collection Wiley Open Access
contents Remarkably Enhancing the Bonding Performance of Aluminum Alloy/ CFRE Hybrid Joints by Directionally Inducing Covalent Bonds and Mechanical Interlocking via Shark Scale Structures and Silane‐Functionalized Interfaces Si Zhang Nuoyi Wu Chuanbo An Zhiying Sun Xu Li Fuying Zhao Xiaoxue Wang Yun Chen Polymer Composites ABSTRACT Interfacial bonding properties critically influence the performance of metal/epoxy composites. This study introduces a surface treatment combining a shark shield scale biomimetic structure and silanization to enhance the interfacial bond strength of aluminum alloy/short carbon fiber reinforced epoxy (CFRE) joints. Surface morphology, roughness, and elemental changes were characterized using laser confocal microscopy and XPS, while wettability and bonding performance were evaluated via contact angle measurements and single‐lap shear tests. The combined treatment increased the initial lap‐shear strength to 12.52 MPa, representing a substantial increase over the pre‐treated baseline (As). Fracture‐surface observations suggest a transition from predominantly interfacial failure toward increased cohesive involvement after the combined treatment. The enhancement is attributed to the synergistic contributions of mechanical interlocking enabled by the shark shield scale texture and a silane‐functionalized interphase that strengthens interfacial interactions (consistent with possible Al–O–Si linkages). This work emphasizes improved initial bonding performance under ambient conditions; durability (e.g., hygrothermal aging, salt spray, and fatigue) will be addressed in future work. 10.1002/pc.70922 http://onlinelibrary.wiley.com/termsAndConditions#vor
doi_str_mv 10.1002/pc.70922
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institution Wiley Open Access
license_str_mv http://onlinelibrary.wiley.com/termsAndConditions#vor
publishDate 2026
publisher Wiley
record_format wiley_oa
spellingShingle Remarkably Enhancing the Bonding Performance of Aluminum Alloy/ CFRE Hybrid Joints by Directionally Inducing Covalent Bonds and Mechanical Interlocking via Shark Scale Structures and Silane‐Functionalized Interfaces
Si Zhang
Nuoyi Wu
Chuanbo An
Zhiying Sun
Xu Li
Fuying Zhao
Xiaoxue Wang
Yun Chen
Polymer Composites
Remarkably Enhancing the Bonding Performance of Aluminum Alloy/ CFRE Hybrid Joints by Directionally Inducing Covalent Bonds and Mechanical Interlocking via Shark Scale Structures and Silane‐Functionalized Interfaces Si Zhang Nuoyi Wu Chuanbo An Zhiying Sun Xu Li Fuying Zhao Xiaoxue Wang Yun Chen Polymer Composites ABSTRACT Interfacial bonding properties critically influence the performance of metal/epoxy composites. This study introduces a surface treatment combining a shark shield scale biomimetic structure and silanization to enhance the interfacial bond strength of aluminum alloy/short carbon fiber reinforced epoxy (CFRE) joints. Surface morphology, roughness, and elemental changes were characterized using laser confocal microscopy and XPS, while wettability and bonding performance were evaluated via contact angle measurements and single‐lap shear tests. The combined treatment increased the initial lap‐shear strength to 12.52 MPa, representing a substantial increase over the pre‐treated baseline (As). Fracture‐surface observations suggest a transition from predominantly interfacial failure toward increased cohesive involvement after the combined treatment. The enhancement is attributed to the synergistic contributions of mechanical interlocking enabled by the shark shield scale texture and a silane‐functionalized interphase that strengthens interfacial interactions (consistent with possible Al–O–Si linkages). This work emphasizes improved initial bonding performance under ambient conditions; durability (e.g., hygrothermal aging, salt spray, and fatigue) will be addressed in future work. 10.1002/pc.70922 http://onlinelibrary.wiley.com/termsAndConditions#vor
title Remarkably Enhancing the Bonding Performance of Aluminum Alloy/ CFRE Hybrid Joints by Directionally Inducing Covalent Bonds and Mechanical Interlocking via Shark Scale Structures and Silane‐Functionalized Interfaces
topic Polymer Composites
url https://4spepublications.onlinelibrary.wiley.com/doi/10.1002/pc.70922