Synthesis, Characterization, and Evaluation of Energetic Properties of 1,2‐bis(5‐(Trifluoromethyl)‐4 H ‐1,2,4‐triazol‐3‐yl)Diazene
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| Natura: | Artículo Open Access |
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Wiley
2025
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| _version_ | 1867010155088969728 |
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| author | Navid Rahman Klas Meyer Werner Kraus Thomas M. Klapötke Tomasz G. Witkowski |
| author_facet | Navid Rahman Klas Meyer Werner Kraus Thomas M. Klapötke Tomasz G. Witkowski Navid Rahman Klas Meyer Werner Kraus Thomas M. Klapötke Tomasz G. Witkowski |
| collection | Wiley Open Access |
| contents | Synthesis, Characterization, and Evaluation of Energetic Properties of 1,2‐bis(5‐(Trifluoromethyl)‐4 H ‐1,2,4‐triazol‐3‐yl)Diazene Navid Rahman Klas Meyer Werner Kraus Thomas M. Klapötke Tomasz G. Witkowski Propellants, Explosives, Pyrotechnics ABSTRACT A new azo‐bridged compound with triazole moieties featuring trifluoromethyl groups was synthesized, exhibiting encouraging properties in the field of energetic materials. The new compound was synthesized in two steps from common starting materials using cyclocondensation, followed by oxidation reaction. The compound was characterized using nuclear magnetic resonance spectroscopy, mass spectrometry, infrared spectroscopy, and single‐crystal X‐ray diffraction. Impact and friction sensitivities were measured using BAM standard methods, and electrostatic discharge (ESD) sensitivity was measured using an ESD device from OZM Research. Heat of formation was calculated computationally using the CBS‐4m method, density was determined by the pycnometric method, and energetic properties were calculated using Explo5 software. 10.1002/prep.70041 http://creativecommons.org/licenses/by/4.0/ |
| doi_str_mv | 10.1002/prep.70041 |
| format | Artículo Open Access |
| id | wiley_oa_10_1002_prep_70041 |
| institution | Wiley Open Access |
| license_str_mv | http://creativecommons.org/licenses/by/4.0/ |
| publishDate | 2025 |
| publisher | Wiley |
| record_format | wiley_oa |
| spellingShingle | Synthesis, Characterization, and Evaluation of Energetic Properties of 1,2‐bis(5‐(Trifluoromethyl)‐4 H ‐1,2,4‐triazol‐3‐yl)Diazene Navid Rahman Klas Meyer Werner Kraus Thomas M. Klapötke Tomasz G. Witkowski Propellants, Explosives, Pyrotechnics Synthesis, Characterization, and Evaluation of Energetic Properties of 1,2‐bis(5‐(Trifluoromethyl)‐4 H ‐1,2,4‐triazol‐3‐yl)Diazene Navid Rahman Klas Meyer Werner Kraus Thomas M. Klapötke Tomasz G. Witkowski Propellants, Explosives, Pyrotechnics ABSTRACT A new azo‐bridged compound with triazole moieties featuring trifluoromethyl groups was synthesized, exhibiting encouraging properties in the field of energetic materials. The new compound was synthesized in two steps from common starting materials using cyclocondensation, followed by oxidation reaction. The compound was characterized using nuclear magnetic resonance spectroscopy, mass spectrometry, infrared spectroscopy, and single‐crystal X‐ray diffraction. Impact and friction sensitivities were measured using BAM standard methods, and electrostatic discharge (ESD) sensitivity was measured using an ESD device from OZM Research. Heat of formation was calculated computationally using the CBS‐4m method, density was determined by the pycnometric method, and energetic properties were calculated using Explo5 software. 10.1002/prep.70041 http://creativecommons.org/licenses/by/4.0/ |
| title | Synthesis, Characterization, and Evaluation of Energetic Properties of 1,2‐bis(5‐(Trifluoromethyl)‐4 H ‐1,2,4‐triazol‐3‐yl)Diazene |
| topic | Propellants, Explosives, Pyrotechnics |
| url | https://onlinelibrary.wiley.com/doi/10.1002/prep.70041 |