Making particle size library of polystyrene latexes prepared through surfactant-free emulsion polymerization: from nano to micronsize
Fuente:
Zenodo
Guardado en:
| Autores principales: | , , |
|---|---|
| Formato: | Recurso digital |
| Lenguaje: | inglés |
| Publicado: |
Zenodo
2023
|
| Materias: | |
| Acceso en línea: | |
| Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
| _version_ | 1866901127128154112 |
|---|---|
| author | Ramezanpour, Maede Nikzad, Elham Rezaee Shirin-Abadi, Abbas |
| author_facet | Ramezanpour, Maede Nikzad, Elham Rezaee Shirin-Abadi, Abbas |
| contents | Polystyrene latexes where the stabilizing moiety originated from I) the inistab (initiator + stabilizer), 4,4'- Azobis(4-cyanopentanoic acid) (ACPA), II) acrylic acid (AA) (in situ copolymerized) or/and III) previously synthesized poly(acrylic acid)-block-polystyrene (PAA-b-PS) were prepared via surfactant-free emulsion polymerization (SFEP). This attitude of incorporating the sodium carboxilate groups (COO?Na+) as negatively charged stabilizing moieties in different materials yield quite different nucleation mechanism. Therefore, the different particle size would be expected. The average size of latex particles were ranged from 1.3 micron to 50nm. Using ACPA as the only stabilizer produced latexes that were ranged from 200nm to 1.3 micron. In contrast, when the stabilizing moieties originated from PAA-b-PS, the latexes exhibited the size below the 100nm. By combining the use of both in situ polymerized ACPA inistab, AA monomer with/without PAA-b-PS, we were able to produce latexes with tunable polystyrene particle sizes. 2023, The Polymer Society, Taipei. |
| format | Recurso digital |
| id | zenodo_https___doi_org_10_1007_s10965-023-03582-0 |
| institution | Zenodo |
| language | eng |
| publishDate | 2023 |
| publisher | Zenodo |
| record_format | zenodo |
| spellingShingle | Making particle size library of polystyrene latexes prepared through surfactant-free emulsion polymerization: from nano to micronsize Ramezanpour, Maede Nikzad, Elham Rezaee Shirin-Abadi, Abbas Nucleation Particle size Surfactant-free emulsion polymerization Polystyrene latexes where the stabilizing moiety originated from I) the inistab (initiator + stabilizer), 4,4'- Azobis(4-cyanopentanoic acid) (ACPA), II) acrylic acid (AA) (in situ copolymerized) or/and III) previously synthesized poly(acrylic acid)-block-polystyrene (PAA-b-PS) were prepared via surfactant-free emulsion polymerization (SFEP). This attitude of incorporating the sodium carboxilate groups (COO?Na+) as negatively charged stabilizing moieties in different materials yield quite different nucleation mechanism. Therefore, the different particle size would be expected. The average size of latex particles were ranged from 1.3 micron to 50nm. Using ACPA as the only stabilizer produced latexes that were ranged from 200nm to 1.3 micron. In contrast, when the stabilizing moieties originated from PAA-b-PS, the latexes exhibited the size below the 100nm. By combining the use of both in situ polymerized ACPA inistab, AA monomer with/without PAA-b-PS, we were able to produce latexes with tunable polystyrene particle sizes. 2023, The Polymer Society, Taipei. |
| title | Making particle size library of polystyrene latexes prepared through surfactant-free emulsion polymerization: from nano to micronsize |
| topic | Nucleation Particle size Surfactant-free emulsion polymerization |
| url | https://doi.org/10.1007/s10965-023-03582-0 |