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| Main Authors: | , , , , , |
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| Format: | Recurso digital |
| Language: | English |
| Published: |
Zenodo
2017
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| Online Access: | https://doi.org/10.1134/S1023193517050123 |
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| _version_ | 1866901129769517056 |
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| author | Moghaddam, Hadi Mahmoudi Beitollahi, Hadi Tajik, Somayeh Jahani, Shohreh Khabazzadeh, Hojatollah Alizadeh, Reza |
| author_facet | Moghaddam, Hadi Mahmoudi Beitollahi, Hadi Tajik, Somayeh Jahani, Shohreh Khabazzadeh, Hojatollah Alizadeh, Reza |
| contents | A novel carbon paste electrode modified with ZnO nanorods and 2-(4-oxo-3-phenyl-3,4-dihydroquinazolinyl)-N?-phenyl-hydrazinecarbothioamide (2PHCZNCPE) was fabricated and employed to study the electrocatalytic oxidation of droxidopa, using cyclic voltammetry, chronoamperometry and square wave voltammetry as diagnostic techniques. It has been found that the oxidation of droxidopa at the surface of modified electrode occurs at a potential of about 435 mV less positive than that of an unmodified carbon paste electrode. Square wave voltammetry exhibits a linear dynamic range from 7.0 108 to 3.010?4 M and a detection limit of 45.0 nM for droxidopa. Finally this modified electrode was used for simultaneous determination of droxidopa and carbidopa. 2017, Pleiades Publishing, Ltd. |
| format | Recurso digital |
| id | zenodo_https___doi_org_10_1134_S1023193517050123 |
| institution | Zenodo |
| language | eng |
| publishDate | 2017 |
| publisher | Zenodo |
| record_format | zenodo |
| spellingShingle | Voltammetric determination of droxidopa in the presence of carbidopa using a nanostructured base electrochemical sensor Moghaddam, Hadi Mahmoudi Beitollahi, Hadi Tajik, Somayeh Jahani, Shohreh Khabazzadeh, Hojatollah Alizadeh, Reza carbidopa carbon paste electrode droxidopa electrocatalysis voltammetric analysis ZnO nanorods A novel carbon paste electrode modified with ZnO nanorods and 2-(4-oxo-3-phenyl-3,4-dihydroquinazolinyl)-N?-phenyl-hydrazinecarbothioamide (2PHCZNCPE) was fabricated and employed to study the electrocatalytic oxidation of droxidopa, using cyclic voltammetry, chronoamperometry and square wave voltammetry as diagnostic techniques. It has been found that the oxidation of droxidopa at the surface of modified electrode occurs at a potential of about 435 mV less positive than that of an unmodified carbon paste electrode. Square wave voltammetry exhibits a linear dynamic range from 7.0 108 to 3.010?4 M and a detection limit of 45.0 nM for droxidopa. Finally this modified electrode was used for simultaneous determination of droxidopa and carbidopa. 2017, Pleiades Publishing, Ltd. |
| title | Voltammetric determination of droxidopa in the presence of carbidopa using a nanostructured base electrochemical sensor |
| topic | carbidopa carbon paste electrode droxidopa electrocatalysis voltammetric analysis ZnO nanorods |
| url | https://doi.org/10.1134/S1023193517050123 |