Luminescent properties of Tb3+- doped P2O5 - Bi2O3 - SrF2 - Na2CO3 glasses for green laser applications

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Main Authors: N. Prasad, P. Chandra Sekhar, T. Chengaiah, B. Deva Prasad Raju
Format: Recurso digital
Published: Zenodo 2025
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author N. Prasad
P. Chandra Sekhar
T. Chengaiah
B. Deva Prasad Raju
author_facet N. Prasad
P. Chandra Sekhar
T. Chengaiah
B. Deva Prasad Raju
contents <p>A series of glass with suitable chemical compositions (60-x) P2O5 + 20 Bi2O3 + 10 SrF2 + 10 Na2CO3 + xTb4O7 (x = 0.1, 0.5, 1.0, 1.5and 2.0% by mole) were prepared by using the melt quenching technique. The X-ray diffraction technique was used to confirm the glass phase structure. The glass matrix's distinct functional groups and distinctive bonding vibrations are revealed by the structural study employing the FTIR technique. The EDAX spectrum was used to examine the elements found in the manufactured glass sample. Photoluminescence (PL) properties of the samples have been examined by excitation, emission and decay patterns. The emission studies revealed a significant green emission at 542 nm, which is associated with the Tb3+ ion's 5D4→7F5 transition. Measurements of the decay curves for the 5D4 level of the Tb3+ ion revealed that they were single exponential in character, independent of the dopant concentration. The CIE chromaticity coordinates were revealed that the green emission was predominant in Tb3+- doped phosphate glasses.</p>
format Recurso digital
id zenodo_https___doi_org_10_5281_zenodo_15674368
institution Zenodo
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publishDate 2025
publisher Zenodo
record_format zenodo
spellingShingle Luminescent properties of Tb3+- doped P2O5 - Bi2O3 - SrF2 - Na2CO3 glasses for green laser applications
N. Prasad
P. Chandra Sekhar
T. Chengaiah
B. Deva Prasad Raju
<p>A series of glass with suitable chemical compositions (60-x) P2O5 + 20 Bi2O3 + 10 SrF2 + 10 Na2CO3 + xTb4O7 (x = 0.1, 0.5, 1.0, 1.5and 2.0% by mole) were prepared by using the melt quenching technique. The X-ray diffraction technique was used to confirm the glass phase structure. The glass matrix's distinct functional groups and distinctive bonding vibrations are revealed by the structural study employing the FTIR technique. The EDAX spectrum was used to examine the elements found in the manufactured glass sample. Photoluminescence (PL) properties of the samples have been examined by excitation, emission and decay patterns. The emission studies revealed a significant green emission at 542 nm, which is associated with the Tb3+ ion's 5D4→7F5 transition. Measurements of the decay curves for the 5D4 level of the Tb3+ ion revealed that they were single exponential in character, independent of the dopant concentration. The CIE chromaticity coordinates were revealed that the green emission was predominant in Tb3+- doped phosphate glasses.</p>
title Luminescent properties of Tb3+- doped P2O5 - Bi2O3 - SrF2 - Na2CO3 glasses for green laser applications
url https://doi.org/10.5281/zenodo.15674368