Comparative Analysis of the Performance of Batteries

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Hauptverfasser: Muhammed, Aniru Abudu, Muhammed, Hibah Imuentinyanose
Format: Recurso digital
Sprache:Englisch
Veröffentlicht: Zenodo 2025
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author Muhammed, Aniru Abudu
Muhammed, Hibah Imuentinyanose
author_facet Muhammed, Aniru Abudu
Muhammed, Hibah Imuentinyanose
contents <p>This study presents a comparative modeling and performance analysis of four major battery chemistries Lead–acid, Lithium-ion, Solid-state, and Flow using MATLAB/Simulink and Simscape. A unified equivalent circuit model (ECM), comprising an open-circuit voltage source, ohmic resistance, and two RC branches, was implemented as a baseline framework to ensure consistency across chemistries. Chemistry-specific extensions were incorporated, including the Shepherd–Peukert model for Lead–acid, a Single-Particle Model (SPM) for Lithium-ion, an extended SPM with interfacial resistance for Solid-state, and coupled tank–stack–channel dynamics for Flow batteries. Experimental OCV–SOC (Open-Circuit Voltage vs. State of Charge) data, diffusion coefficients, and kinetic parameters were integrated to enhance fidelity, while degradation sub-models such as SEI growth, Peukert aging, interfacial resistance, and electrolyte imbalance enabled lifecycle projections. Standardized test protocols comprising constant-current discharges, dynamic load cycles, temperature sweeps, and cycling tests were applied to evaluate voltage–SOC behaviour, round-trip efficiency, thermal rise, and cycle life. Results indicated that Lithium-ion and Solid-state deliver superior energy density and efficiency, Lead–acid remains cost-effective but cycle-limited, and Flow batteries achieve exceptional lifetime with scalable power–energy decoupling. The unified framework provides a reproducible methodology for battery evaluation, offering valuable insights for mobility, stationary storage, and grid-scale applications.</p>
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id zenodo_https___doi_org_10_5281_zenodo_18267961
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language eng
publishDate 2025
publisher Zenodo
record_format zenodo
spellingShingle Comparative Analysis of the Performance of Batteries
Muhammed, Aniru Abudu
Muhammed, Hibah Imuentinyanose
Battery modeling
MATLAB/Simulink
Lithium-ion
Solid-state
Flow battery
<p>This study presents a comparative modeling and performance analysis of four major battery chemistries Lead–acid, Lithium-ion, Solid-state, and Flow using MATLAB/Simulink and Simscape. A unified equivalent circuit model (ECM), comprising an open-circuit voltage source, ohmic resistance, and two RC branches, was implemented as a baseline framework to ensure consistency across chemistries. Chemistry-specific extensions were incorporated, including the Shepherd–Peukert model for Lead–acid, a Single-Particle Model (SPM) for Lithium-ion, an extended SPM with interfacial resistance for Solid-state, and coupled tank–stack–channel dynamics for Flow batteries. Experimental OCV–SOC (Open-Circuit Voltage vs. State of Charge) data, diffusion coefficients, and kinetic parameters were integrated to enhance fidelity, while degradation sub-models such as SEI growth, Peukert aging, interfacial resistance, and electrolyte imbalance enabled lifecycle projections. Standardized test protocols comprising constant-current discharges, dynamic load cycles, temperature sweeps, and cycling tests were applied to evaluate voltage–SOC behaviour, round-trip efficiency, thermal rise, and cycle life. Results indicated that Lithium-ion and Solid-state deliver superior energy density and efficiency, Lead–acid remains cost-effective but cycle-limited, and Flow batteries achieve exceptional lifetime with scalable power–energy decoupling. The unified framework provides a reproducible methodology for battery evaluation, offering valuable insights for mobility, stationary storage, and grid-scale applications.</p>
title Comparative Analysis of the Performance of Batteries
topic Battery modeling
MATLAB/Simulink
Lithium-ion
Solid-state
Flow battery
url https://doi.org/10.5281/zenodo.18267961