D3.2 Lab scale Raman test report

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Main Author: Aleksanyan, Artur
Format: Recurso digital
Language:English
Published: Zenodo 2025
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_version_ 1866902137976389632
author Aleksanyan, Artur
author_facet Aleksanyan, Artur
contents <p>As part of the DELYCIOUS project, a Raman gas analyser prototype was developed and calibrated using<br>certified gas mixtures to ensure accurate detection of hydrogen (H₂), oxygen (O₂), nitrogen (N₂), and<br>water vapor (H₂O). Calibration was performed with Horiba’s Astra H2 software, which enables intuitive<br>workflow setup and recalibration using minimal amount of reference gases.<br>Each gas was calibrated using at least two reference points for a full-scale measurement (0 to 100%).<br>This method ensures reliable performance and easy recalibration at client sites.<br>Key results:<br>• The analyser accurately measured dry and humid gas mixtures with a limit of detection (LOD)<br>of 1% and with acquisition times optimized at 3–4 seconds.<br>• In humid mixtures, the analyser successfully identified water vapor peaks and quantified concentrations<br>of gas matrix. Raman gas analyser prototype is not compatible with liquid water;<br>hence, it needs to be removed from the gas stream before the measurements.<br>• The system supports both quantitative and qualitative gas detection, including low concentration<br>components below 1%. Quantitative measurement allows for monitoring the concentration<br>dynamics in the framework of manipulations with electrolysers. Qualitative measurement<br>gives additional information about the composition of the gas matrix which could be crucial to<br>detect; Indeed, contaminants and undesirable chemical components can potentially deteriorate<br>the stack.</p>
format Recurso digital
id zenodo_https___doi_org_10_5281_zenodo_18538951
institution Zenodo
language eng
publishDate 2025
publisher Zenodo
record_format zenodo
spellingShingle D3.2 Lab scale Raman test report
Aleksanyan, Artur
Raman spectroscopy
electrolysis
Hydrogen
gas detection
analytical chemistry
<p>As part of the DELYCIOUS project, a Raman gas analyser prototype was developed and calibrated using<br>certified gas mixtures to ensure accurate detection of hydrogen (H₂), oxygen (O₂), nitrogen (N₂), and<br>water vapor (H₂O). Calibration was performed with Horiba’s Astra H2 software, which enables intuitive<br>workflow setup and recalibration using minimal amount of reference gases.<br>Each gas was calibrated using at least two reference points for a full-scale measurement (0 to 100%).<br>This method ensures reliable performance and easy recalibration at client sites.<br>Key results:<br>• The analyser accurately measured dry and humid gas mixtures with a limit of detection (LOD)<br>of 1% and with acquisition times optimized at 3–4 seconds.<br>• In humid mixtures, the analyser successfully identified water vapor peaks and quantified concentrations<br>of gas matrix. Raman gas analyser prototype is not compatible with liquid water;<br>hence, it needs to be removed from the gas stream before the measurements.<br>• The system supports both quantitative and qualitative gas detection, including low concentration<br>components below 1%. Quantitative measurement allows for monitoring the concentration<br>dynamics in the framework of manipulations with electrolysers. Qualitative measurement<br>gives additional information about the composition of the gas matrix which could be crucial to<br>detect; Indeed, contaminants and undesirable chemical components can potentially deteriorate<br>the stack.</p>
title D3.2 Lab scale Raman test report
topic Raman spectroscopy
electrolysis
Hydrogen
gas detection
analytical chemistry
url https://doi.org/10.5281/zenodo.18538951