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Zenodo
2026
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| Online Access: | https://doi.org/10.5281/zenodo.19662503 |
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| author | Zawadzki, Bartosz Valaskova, Marta Martaus, Alexandr Pavlovsky, Jiri Koci, Kamila |
| author_facet | Zawadzki, Bartosz Valaskova, Marta Martaus, Alexandr Pavlovsky, Jiri Koci, Kamila |
| contents | <p>This study investigates the efficiency of sodium-doped NiO/vermiculite (Vm) composites as photocatalysts for hydrogen production via methanol-water decomposition under UV irradiation. Using natural vermiculite as a support, NiO was introduced as a p-type semiconductor, and sodium doping was achieved using sodium hydroxide (NaOH) or sodium nitrate (NaNO 3 ). Three synthesis methods - dry synthesis by milling, capillary impregnation, and wet impregnation were investigated for their influence on the structural, textural, optical, and electrical properties and the photocatalytic activity. Characterization techniques, including X-ray fluorescence, X-ray diffraction, atomic absorption spectrometry, photoluminescence, scanning electron microscopy with energy dispersive X-ray spectroscopy confirmed successful incorporation of NiO and sodium into the vermiculite matrix. Photocatalytic tests demonstrated that sodium doping enhances the stability and activity of the photocatalysts by reducing electron-hole recombination rates, with NaOH proving to be a more effective sodium source than NaNO 3 . Among the samples, those synthesized via capillary impregnation (NiO(OH)/Vm-C) and dry synthesis (NiO(OH)/Vm-M) showed the highest hydrogen yields (550 and 540 μ mol/g cat., respectively) due to optimal crystallite size (~22–23 nm) and defect-induced charge transfer efficiency. This is the first study to systematically investigate the role of sodium doping in NiO/clay-based photocatalysts and to reveal clear structure–property–activity correlations based on synthesis method and dopant type. The findings highlight the potential of Na-doped NiO/Vm composites as cost-effective and scalable photocatalysts for hydrogen production. The insights gained here lay the foundation for further development of layered, clay-supported photocatalysts beyond conventional oxide systems.</p> |
| format | Recurso digital |
| id | zenodo_https___doi_org_10_5281_zenodo_19662503 |
| institution | Zenodo |
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| publishDate | 2026 |
| publisher | Zenodo |
| record_format | zenodo |
| spellingShingle | Effect of sodium doping in NiO/Vermiculite composite on photocatalytic hydrogen production from methanol-water decomposition Zawadzki, Bartosz Valaskova, Marta Martaus, Alexandr Pavlovsky, Jiri Koci, Kamila <p>This study investigates the efficiency of sodium-doped NiO/vermiculite (Vm) composites as photocatalysts for hydrogen production via methanol-water decomposition under UV irradiation. Using natural vermiculite as a support, NiO was introduced as a p-type semiconductor, and sodium doping was achieved using sodium hydroxide (NaOH) or sodium nitrate (NaNO 3 ). Three synthesis methods - dry synthesis by milling, capillary impregnation, and wet impregnation were investigated for their influence on the structural, textural, optical, and electrical properties and the photocatalytic activity. Characterization techniques, including X-ray fluorescence, X-ray diffraction, atomic absorption spectrometry, photoluminescence, scanning electron microscopy with energy dispersive X-ray spectroscopy confirmed successful incorporation of NiO and sodium into the vermiculite matrix. Photocatalytic tests demonstrated that sodium doping enhances the stability and activity of the photocatalysts by reducing electron-hole recombination rates, with NaOH proving to be a more effective sodium source than NaNO 3 . Among the samples, those synthesized via capillary impregnation (NiO(OH)/Vm-C) and dry synthesis (NiO(OH)/Vm-M) showed the highest hydrogen yields (550 and 540 μ mol/g cat., respectively) due to optimal crystallite size (~22–23 nm) and defect-induced charge transfer efficiency. This is the first study to systematically investigate the role of sodium doping in NiO/clay-based photocatalysts and to reveal clear structure–property–activity correlations based on synthesis method and dopant type. The findings highlight the potential of Na-doped NiO/Vm composites as cost-effective and scalable photocatalysts for hydrogen production. The insights gained here lay the foundation for further development of layered, clay-supported photocatalysts beyond conventional oxide systems.</p> |
| title | Effect of sodium doping in NiO/Vermiculite composite on photocatalytic hydrogen production from methanol-water decomposition |
| url | https://doi.org/10.5281/zenodo.19662503 |